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Acta Cryst. (2013). E69, o1045-o1046  [ doi:10.1107/S160053681301533X ]


S. K. Devi, T. Srinivasan, J. N. S. Rao, R. Raghunathan and D. Velmurugan

Abstract: In the title compound, C29H23N3O4, the 2-methylpyrrolidine ring adopts a twist conformation on the N-C bond involving the spiro C atom, while the hydropyran ring adopts an envelope conformation with the methine C atom bonded to the O atom as the flap. The mean plane of the indoline-2-one ring system is almost perpendicular to the mean plane of the pyrrolidine ring, making a dihedral angle of 89.73 (8)°. The latter ring makes dihedral angles of 47.80 (8) with the naphthalene ring system and 32.38 (8)° with the hydropyran ring mean plane. There is an intramolecular C-H...O hydrogen bond involving the indoline-2-one O atom. In the crystal, adjacent molecules are linked via N-H...O hydrogen bonds, forming chains propagating along [100]. The chains are linked via weak C-H...O hydrogen bonds, forming two-dimensional networks, lying parallel to (101), and consolidated by C-H...[pi] interactions.

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