Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 7 (July 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m405    [ doi:10.1107/S1600536813016681 ]


M. A. Benaouida, A. Benosmane, H. Bouguerria, S. E. Bouaoud and H. Merazig

Abstract: The CuII atom in the title compound, [Cu(C16H10ClN2O)2], is located on an inversion center and is tetra­coordinated by two N and two O atoms from two bidentate 1-[(E)-(2-chloro­phen­yl)diazen­yl]naphthalen-2-olate ligands, forming a square-planar complex. In the crystal, mol­ecules are linked via weak C-H...O and C-H...Cl hydrogen bonds, forming chains propagating along [010]. There are also [pi]-[pi] inter­actions present involving adjacent naphthalene rings [centroid-centroid distance = 3.661 (13) Å].

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