[Journal logo]

Volume 69 
Part 7 
Page m372  
July 2013  

Received 23 May 2013
Accepted 31 May 2013
Online 8 June 2013

Key indicators
Single-crystal X-ray study
T = 291 K
Mean [sigma](C-C) = 0.007 Å
R = 0.032
wR = 0.063
Data-to-parameter ratio = 15.2
Details
Open access

Chlorido{1-[(dimethylamino)methyl]ferrocenyl-[kappa]2C2,N}(triphenylstibine-[kappa]Sb)palladium(II)

aInstituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior s/n Ciudad Universitaria, 04510, México D.F., México, and bIngeniería Bioquímica, Instituto Tecnológico Superior de Atlixco, Atlixco, Puebla, México
Correspondence e-mail: pankajsh@unam.mx

In the title compound, [FePdCl(C5H5)(C8H11N)(C18H15Sb)], obtained by reaction of diphenyl(N,N-dimethylaminomethylferrocenyl)stibine with sodium tetrachloridopalladate(II) in acetone, the PdII atom is coordinated in a slightly distorted square-planar geometry by a C atom of the ferrocenyl ring, and by N, Cl and Sb atoms. The Sb and N atoms are trans to each other.

Related literature

For the use of 1,2-disubstituted ferrocenylphosphines as catalytic precursors, see: Sokolov et al. (2005[Sokolov, M. N., Chubarova, E. V., Hernández-Molina, R., Clausen, M., Naumov, D., Vincent, C., Lusar, R. & Vladimir, P. (2005). Eur. J. Inorg. Chem. 11, 2139-2146.]); Zirakzadeh et al. (2012[Zirakzadeh, A., Schuecker, R., Gorgas, N., Mereiter, K., Spindler, F. & Weissensteiner, W. (2012). Organometallics, 31, 4241-4250.]). For Pd-Sb bond lengths in related compounds, see: Mentes & Fawcett (2005[Mentes, A. & Fawcett, J. (2005). Inorg. Chim. Acta. C358, 1279-1283.]).

[Scheme 1]

Experimental

Crystal data
  • [FePdCl(C5H5)(C8H11N)(C18H15Sb)]

  • Mr = 737.02

  • Monoclinic, P 21 /c

  • a = 10.3138 (6) Å

  • b = 19.8865 (12) Å

  • c = 13.7584 (9) Å

  • [beta] = 92.984 (1)°

  • V = 2818.1 (3) Å3

  • Z = 4

  • Mo K[alpha] radiation

  • [mu] = 2.21 mm-1

  • T = 291 K

  • 0.36 × 0.12 × 0.10 mm

Data collection
  • Bruker SMART APEX CCD area-detector diffractometer

  • Absorption correction: analytical (SADABS; Bruker, 2007[Bruker (2007). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.490, Tmax = 0.797

  • 23494 measured reflections

  • 5158 independent reflections

  • 4107 reflections with I > 2[sigma](I)

  • Rint = 0.048

Refinement
  • R[F2 > 2[sigma](F2)] = 0.032

  • wR(F2) = 0.063

  • S = 0.93

  • 4963 reflections

  • 327 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 0.77 e Å-3

  • [Delta][rho]min = -0.31 e Å-3

Table 1
Selected bond lengths (Å)

Sb1-C14 2.127 (4)
Sb1-C20 2.120 (4)
Sb1-C26 2.119 (4)
Sb1-Pd1 2.4853 (4)
Pd1-C1 1.973 (4)
Pd1-Cl1 2.3952 (10)
Pd1-N1 2.174 (3)

Data collection: SMART (Bruker, 2007[Bruker (2007). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2007[Bruker (2007). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: VN2072 ).


Acknowledgements

The authors thank the Dirección General de Asuntos del Personal Académico-UNAM project No. IN-223013 for financial support.

References

Bruker (2007). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Mentes, A. & Fawcett, J. (2005). Inorg. Chim. Acta. C358, 1279-1283.  [Web of Science] [CSD] [CrossRef]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [ChemPort] [IUCr Journals]
Sokolov, M. N., Chubarova, E. V., Hernández-Molina, R., Clausen, M., Naumov, D., Vincent, C., Lusar, R. & Vladimir, P. (2005). Eur. J. Inorg. Chem. 11, 2139-2146.  [Web of Science] [CSD] [CrossRef]
Zirakzadeh, A., Schuecker, R., Gorgas, N., Mereiter, K., Spindler, F. & Weissensteiner, W. (2012). Organometallics, 31, 4241-4250.  [CSD] [CrossRef] [ChemPort]


Acta Cryst (2013). E69, m372  [ doi:10.1107/S1600536813015109 ]

This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.