Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 7 (July 2013)


metal-organic compounds



vn2073 scheme

Acta Cryst. (2013). E69, m404    [ doi:10.1107/S1600536813016450 ]

Chlorido[2,2'-[1,2-phenylenebis(nitrilomethanylylidyne)]diphenolato-[kappa]4O,N,N',O']manganese(III) methanol monosolvate

H. Lin, J.-G. Wang, H.-T. Shi, Q. Chen and Q.-F. Zhang

Abstract: In the title complex, [Mn(C20H14N2O2)Cl]·CH3OH, the central MnIII atom displays a distorted square-pyramidal coordination by two N and two O atoms from the tetradentate 2,2'-[1,2-phenylenebis(nitrilomethanylylidyne)]diphenolate ligand and one chloride ligand. The MnIII atom is 0.525 (4) Å out of the square basal N2O2 least-squares plane. The complex molecule is hydrogen bonded to the methanol solvent molecule.


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