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Volume 69 
Part 7 
Page m404  
July 2013  

Received 31 May 2013
Accepted 13 June 2013
Online 19 June 2013

Key indicators
Single-crystal X-ray study
T = 296 K
Mean [sigma](C-C) = 0.003 Å
R = 0.035
wR = 0.086
Data-to-parameter ratio = 16.9
Details
Open access

Chlorido[2,2'-[1,2-phenylenebis(nitrilomethanylylidyne)]diphenolato-[kappa]4O,N,N',O']manganese(III) methanol monosolvate

aInstitute of Molecular Engineering and Applied Chemsitry, Anhui University of Technology, Ma'anshan, Anhui 243002, People's Republic of China, and bDepartment of Applied Chemistry, School of Petrochemical Engineering, Changzhou University, Jiangsu 213164, People's Republic of China
Correspondence e-mail: zhangqf@ahut.edu.cn

In the title complex, [Mn(C20H14N2O2)Cl]·CH3OH, the central MnIII atom displays a distorted square-pyramidal coordination by two N and two O atoms from the tetradentate 2,2'-[1,2-phenylenebis(nitrilomethanylylidyne)]diphenolate ligand and one chloride ligand. The MnIII atom is 0.525 (4) Å out of the square basal N2O2 least-squares plane. The complex molecule is hydrogen bonded to the methanol solvent molecule.

Related literature

For background to manganese and manganese-salen complexes, see: Law et al. (1998[Law, N. A., Caudle, M. T. & Pecoraro, V. L. (1998). Adv. Inorg. Chem. 46, 305-440.]); Lenoble et al. (1998[Lenoble, G., Lacroix, P. G., Daran, J. C., Bella, S. D. & Nakatani, K. (1998). Inorg. Chem. 37, 2158-2165.]); Horner et al. (1999[Horner, O., Mallart, E. A., Charlot, M.-F., Tchertanov, L., Guilhem, J., Mattioli, T. A., Boussac, A. & Girerd, J.-J. (1999). Inorg. Chem. 38, 1222-1232.]); Asada et al. (2000[Asada, H., Fujiwara, M. & Matsushita, T. (2000). Polyhedron, 19, 2039-2048.]); Dubois et al. (2003[Dubois, L., Xiang, D.-F., Tan, X.-S., Pecaut, J., Jones, P., Baudron, S., Pape, L. L., Latour, J. M., Baffert, C., Noblat, S. C., Collomb, M. N. & Deronzier, A. (2003). Inorg. Chem. 42, 750-760.]); Gultneh et al. (2003[Gultneh, Y., Yisgedu, T. B., Tesema, Y. T. & Butcher, R. J. (2003). Inorg. Chem. 42, 1857-1867.]); Mitra et al. (2006[Mitra, K., Biswas, S., Lucas, C. R. & Adhikary, B. (2006). Inorg. Chim. Acta, 359, 1997-2003.]). For related structures, see: Pecoraro & Butler (1986[Pecoraro, V. L. & Butler, W. M. (1986). Acta Cryst. C42, 1151-1154.]); Dang et al. (2005[Dang, L.-L., Huo, Y.-Q., Wang, W. & Li, J. (2005). Acta Cryst. E61, m332-m334.]); Martínez et al. (2002[Martínez, D., Motevalli, M. & Watkinson, M. (2002). Acta Cryst. C58, m258-m260.]); Panja et al. (2003[Panja, A., Shaikh, N., Ali, M., Vojtisek, P. & Banerjee, P. (2003). Polyhedron, 22, 1191-1198.]).

[Scheme 1]

Experimental

Crystal data
  • [Mn(C20H14N2O2)Cl]·CH4O

  • Mr = 436.76

  • Triclinic, [P \overline 1]

  • a = 7.4251 (2) Å

  • b = 9.8341 (2) Å

  • c = 13.3035 (3) Å

  • [alpha] = 78.803 (1)°

  • [beta] = 83.305 (2)°

  • [gamma] = 86.344 (2)°

  • V = 945.58 (4) Å3

  • Z = 2

  • Mo K[alpha] radiation

  • [mu] = 0.87 mm-1

  • T = 296 K

  • 0.24 × 0.17 × 0.13 mm

Data collection
  • Bruker SMART APEXII CCD area-detector diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2001[Bruker (2001). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.819, Tmax = 0.896

  • 17011 measured reflections

  • 4302 independent reflections

  • 3311 reflections with I > 2[sigma](I)

  • Rint = 0.032

Refinement
  • R[F2 > 2[sigma](F2)] = 0.035

  • wR(F2) = 0.086

  • S = 1.02

  • 4302 reflections

  • 255 parameters

  • 1 restraint

  • H-atom parameters constrained

  • [Delta][rho]max = 0.33 e Å-3

  • [Delta][rho]min = -0.40 e Å-3

Table 1
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
O1S-H1S...O1i 0.87 2.19 2.999 (3) 154
Symmetry code: (i) x+1, y, z.

Data collection: APEX2 (Bruker, 2007[Bruker (2007). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2007[Bruker (2007). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: SHELXTL.


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: VN2073 ).


Acknowledgements

This project was supported by the Natural Science Foundation of China (90922008).

References

Asada, H., Fujiwara, M. & Matsushita, T. (2000). Polyhedron, 19, 2039-2048.  [Web of Science] [CSD] [CrossRef] [ChemPort]
Bruker (2001). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Bruker (2007). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
Dang, L.-L., Huo, Y.-Q., Wang, W. & Li, J. (2005). Acta Cryst. E61, m332-m334.  [CSD] [CrossRef] [ChemPort] [IUCr Journals]
Dubois, L., Xiang, D.-F., Tan, X.-S., Pecaut, J., Jones, P., Baudron, S., Pape, L. L., Latour, J. M., Baffert, C., Noblat, S. C., Collomb, M. N. & Deronzier, A. (2003). Inorg. Chem. 42, 750-760.  [Web of Science] [CSD] [CrossRef] [PubMed] [ChemPort]
Gultneh, Y., Yisgedu, T. B., Tesema, Y. T. & Butcher, R. J. (2003). Inorg. Chem. 42, 1857-1867.  [Web of Science] [CSD] [CrossRef] [PubMed] [ChemPort]
Horner, O., Mallart, E. A., Charlot, M.-F., Tchertanov, L., Guilhem, J., Mattioli, T. A., Boussac, A. & Girerd, J.-J. (1999). Inorg. Chem. 38, 1222-1232.  [Web of Science] [CrossRef] [PubMed] [ChemPort]
Law, N. A., Caudle, M. T. & Pecoraro, V. L. (1998). Adv. Inorg. Chem. 46, 305-440.  [CrossRef] [ChemPort]
Lenoble, G., Lacroix, P. G., Daran, J. C., Bella, S. D. & Nakatani, K. (1998). Inorg. Chem. 37, 2158-2165.  [Web of Science] [CrossRef] [PubMed] [ChemPort]
Martínez, D., Motevalli, M. & Watkinson, M. (2002). Acta Cryst. C58, m258-m260.  [CSD] [CrossRef] [IUCr Journals]
Mitra, K., Biswas, S., Lucas, C. R. & Adhikary, B. (2006). Inorg. Chim. Acta, 359, 1997-2003.  [Web of Science] [CrossRef] [ChemPort]
Panja, A., Shaikh, N., Ali, M., Vojtisek, P. & Banerjee, P. (2003). Polyhedron, 22, 1191-1198.  [Web of Science] [CSD] [CrossRef] [ChemPort]
Pecoraro, V. L. & Butler, W. M. (1986). Acta Cryst. C42, 1151-1154.  [CrossRef] [IUCr Journals]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [ChemPort] [IUCr Journals]


Acta Cryst (2013). E69, m404  [ doi:10.1107/S1600536813016450 ]

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