Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 7 (July 2013)


metal-organic compounds



vn2074 scheme

Acta Cryst. (2013). E69, m408-m409    [ doi:10.1107/S1600536813016735 ]

cis-Bis(O-methyldithiocarbonato-[kappa]2S,S')bis(triphenylphosphane-[kappa]P)ruthenium(II)

C. Valerio-Cárdenas, S. Hernández-Ortega, R. Reyes-Martínez and D. Morales-Morales

Abstract: In the title compound, [Ru(CH3OCS2)2(C18H15P)2], the RuII atom is in a distorted octahedral coordination by two xanthate anions (CH3OCS2) and two triphenylphosphane (PPh3) ligands. Both bidentate xanthate ligands coordinate the RuII atom with two slightly different Ru-S bond lengths but with virtually equal bite angles [71.57 (4) and 71.58 (3)°]. The packing of the complexes is assured by C-H...O and C-H...[pi] interactions.


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