Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 7 (July 2013)


metal-organic compounds



wm2747 scheme

Acta Cryst. (2013). E69, m399    [ doi:10.1107/S1600536813016188 ]

Diaqua{2,2'-dimethoxy-6,6'-[(1E,1'E)-propane-1,3-diylbis(azanylylidene)bis(methanylylidene)]diphenolato}nickel(II)

A. Datta, B. Machura, J.-H. Huang and S.-C. Sheu

Abstract: In the molecule of the title compound, [Ni(C19H20N2O4)(H2O)2], the central NiII ion lies on a mirror plane and is surrounded by an N2O4 coordination set in the form of a distorted octahedron defined by the O atoms of two water molecules and by two phenolic O and two imine N atoms of the tetradentate Schiff base ligand. In the crystal, O-H...O hydrogen bonds between the water molecules and the phenolic and methoxy O atoms of neighbouring molecules lead to the formation of rods propagating parallel to [100].


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