Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 7 (July 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m399    [ doi:10.1107/S1600536813016188 ]


A. Datta, B. Machura, J.-H. Huang and S.-C. Sheu

Abstract: In the mol­ecule of the title compound, [Ni(C19H20N2O4)(H2O)2], the central NiII ion lies on a mirror plane and is surrounded by an N2O4 coordination set in the form of a distorted octa­hedron defined by the O atoms of two water mol­ecules and by two phenolic O and two imine N atoms of the tetra­dentate Schiff base ligand. In the crystal, O-H...O hydrogen bonds between the water mol­ecules and the phenolic and meth­oxy O atoms of neighbouring mol­ecules lead to the formation of rods propagating parallel to [100].

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