Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 7 (July 2013)


metal-organic compounds



wm2748 scheme

Acta Cryst. (2013). E69, m395-m396    [ doi:10.1107/S160053681301622X ]

cis-Dichloridotetrakis(dimethyl sulfoxide-[kappa]O)chromium(III) chloride dimethyl sulfoxide monosolvate

N. A. Al-Najjar, A.-R. H. Al-Sudani, M. A. Shanshal, F. H. Mousa and B. M. Kariuki

Abstract: The structure of the title compound, [CrCl2(C2H6OS)4]Cl·C2H6OS, consists of a CrIII ion coordinated by four O atoms of dimethyl sulfoxide (DMSO) ligands and two chloride ions in cis positions, forming a distorted CrCl2O4 octahedron. An isolated Cl- counter-anion and a positionally disordered DMSO molecule [occupancy ratio 0.654 (4):0.346 (4)] are also present. In the structure, the complex cations interact with the Cl- counter-anions and the DMSO solvent molecules via weak C-H...Cl and C-H...O interactions, forming a three-dimensional network.


htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file
[ doi:10.1107/S160053681301622X/wm2748sup0.html ]
Supplementary materials


Notes:

To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster