Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 7 (July 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m422-m423    [ doi:10.1107/S1600536813017388 ]


J. P. Martins, C. C. Arranja, A. J. F. N. Sobral and M. Ramos Silva

Abstract: In the title compound, [K(C10H5ClO2F3)(H2O)]n, the two independent K+ ions are located on a twofold rotation axis. For each of the cations, the distorted cubic coordination environment is defined by two F and four O atoms of symmetry-related 1,4-chloro­phenyl-4,4,4-tri­fluoro­butane-1,3-dionate anions and by two O atoms of water mol­ecules. The [mu]4-bridging character of the anion and the [mu]2-bridging of the water mol­ecule lead to the formation of layers parallel to (100). The coordinating water mol­ecules are also involved in O-H...O hydrogen bonds that reinforce the mol­ecular cohesion within the layers, which are stacked along [100]. The [beta]-diketonate anion is not planar, with an angle of 31.78 (10)° between the mean planes of the diketonate group and the chloro­phenyl ring.

htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file
[ doi:10.1107/S1600536813017388/wm2752sup0.html ]
Supplementary materials


To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster