Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 7 (July 2013)


metal-organic compounds



xu5711 scheme

Acta Cryst. (2013). E69, m381-m382    [ doi:10.1107/S160053681301564X ]

catena-Poly[aquabis([mu]-3-chlorobenzoato-[kappa]2O:O')zinc]

N. Bozkurt, N. Dilek, N. Çaylak Delibas, H. Necefoglu and T. Hökelek

Abstract: In the polymeric title compound, [Zn(C7H4ClO2)2(H2O)]n, the ZnII cation is located on a twofold rotation axis and is coordinated by carboxylate O atoms of four monodentate chlorobenzoate anions and by one water molecule, located on a twofold rotation axis, in a distorted square-pyramidal geometry. In the anion, the carboxylate group is twisted away from the attached benzene ring by 44.16 (11)°. The chlorobenzoate anion bridges ZnII cations, forming polymeric chains running along the c-axis direction. O-H...O hydrogen bonds between coordinating water molecules and carboxylate groups link adjacent chains into layers parallel to the bc plane.


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