Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 7 (July 2013)


metal-organic compounds



zl2553 scheme

Acta Cryst. (2013). E69, m398    [ doi:10.1107/S1600536813015870 ]

Poly[(acetonitrile-[kappa]N)-[mu]3-thiocyanato-[kappa]3N:S:S-[mu]2-thiocyanato-[kappa]2N:S-cadmium]

T. Reinert, I. Jess and C. Näther

Abstract: The asymmetric unit of the title compound, [Cd(NCS)2(CH3CN)]n, consists of one CdII cation, two thiocyanate anions and one acetonitrile ligand, all in general positions. The CdII cation is coordinated by three N atoms of two thiocyanate anions and one acetonitrile ligand, as well as three S atoms of symmetry-related thiocyanate anions within a slightly distorted octahedral coordination environment. The CdII cations are linked by [mu]-1,3(N,S) and [mu]-1,1,3(S,S,N) thiocyanate anions into layers that are located in the ab plane.


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