Acta Cryst. (2013). E69, m398 [ doi:10.1107/S1600536813015870 ]
Abstract: The asymmetric unit of the title compound, [Cd(NCS)2(CH3CN)]n, consists of one CdII cation, two thiocyanate anions and one acetonitrile ligand, all in general positions. The CdII cation is coordinated by three N atoms of two thiocyanate anions and one acetonitrile ligand, as well as three S atoms of symmetry-related thiocyanate anions within a slightly distorted octahedral coordination environment. The CdII cations are linked by -1,3(N,S) and -1,1,3(S,S,N) thiocyanate anions into layers that are located in the ab plane.
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