Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 7 (July 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m398    [ doi:10.1107/S1600536813015870 ]


T. Reinert, I. Jess and C. Näther

Abstract: The asymmetric unit of the title compound, [Cd(NCS)2(CH3CN)]n, consists of one CdII cation, two thio­cyanate anions and one aceto­nitrile ligand, all in general positions. The CdII cation is coordinated by three N atoms of two thio­cyanate anions and one aceto­nitrile ligand, as well as three S atoms of symmetry-related thio­cyanate anions within a slightly distorted octa­hedral coordination environment. The CdII cations are linked by [mu]-1,3(N,S) and [mu]-1,1,3(S,S,N) thio­cyanate anions into layers that are located in the ab plane.

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