Received 6 June 2013
In the racemic title compound, C14H16BrNO3S2, synthesized from the corresponding -bromopropiophenone, the dihedral angle between the plane of the phenol group and that of the planar section [maximum deviation = 0.040 (2) Å] of the morpholine-4-carbodithiolate moiety is 76.36 (10)°. A strong intramolecular phenol O-HO hydrogen bond if present in the molecule. In the crystal, only weak C-HS and C-HO interactions are found.
For the synthesis and applications of dithiocarbamates, see: Buu-Hoi & Lavit (1955); WHO (1998). For applications of 1,3-dithiolium salts, see: Narita & Pittman (1976); Birsa & Asaftei (2008). For the structure of a related morpholine-4-carbodithioate, see: Bahrin et al. (2012).
Data collection: X-AREA (Stoe & Cie, 2002); cell refinement: X-AREA; data reduction: X-RED (Stoe & Cie, 2002); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: XP in SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXL97.
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: ZS2265 ).
Part of this work was supported by a grant of the Romanian National Authority for Scientific Research, CNDI-UEFISCDI, project No. 51/2012.
Bahrin, L. G., Jones, P. G. & Hopf, H. (2012). Beilstein J. Org. Chem. 8, 1999-2003.
Birsa, M. L. & Asaftei, I. V. (2008). Monatsh. Chem. 139, 1433-1438.
Buu-Hoi, Ng. Ph. & Lavit, D. (1955). J. Chem. Soc., pp. 18-20.
Dwiggins, C. W. (1975). Acta Cryst. A31, 146-148.
Narita, M. & Pittman, C. U. Jr (1976). Synthesis, pp. 489-514.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.
Stoe & Cie (2002). X-AREA and X-RED. Stoe & Cie, Darmstadt, Germany.
WHO (1998). http://www.inchem.org/documents/ehc/ehc/ehc78.htm .