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Acta Cryst. (2013). E69, o1170  [ doi:10.1107/S1600536813017510 ]

4-Bromo-2-[5-methyl-2-(morpholin-4-yl)-1,3-thiazol-4-yl]phenol

L. G. Bahrin, C. G. Hrib and L. M. Birsa

Abstract: In the title compound, C14H15BrN2O2S, synthesized by the reaction of the corresponding phenacyl thiocyanate with morpholine, the dihedral angle between the 1,3-thiazole ring and the phenolic substituent ring is 23.46 (10)° as a result of the steric influence of the ortho-methyl group on the thiazole ring. A strong intramolecular phenolic O-H...N hydrogen bond is present in the molecule. In the crystal, a weak C-H...Ophenol hydrogen bond gives rise to chains lying parallel to [20-1]. A short intermolecular Br...Omorpholine interaction is also present [3.1338 (19) Å].


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