Acta Cryst. (2013). E69, o1170
[ doi:10.1107/S1600536813017510 ]
Abstract: In the title compound, C14H15BrN2O2S, synthesized by the reaction of the corresponding phenacyl thiocyanate with morpholine, the dihedral angle between the 1,3-thiazole ring and the phenolic substituent ring is 23.46 (10)° as a result of the steric influence of the ortho-methyl group on the thiazole ring. A strong intramolecular phenolic O-HN hydrogen bond is present in the molecule. In the crystal, a weak C-HOphenol hydrogen bond gives rise to chains lying parallel to [20-1]. A short intermolecular BrOmorpholine interaction is also present [3.1338 (19) Å].
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