Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 8 (August 2013)

organic compounds

Acta Cryst. (2013). E69, o1293-o1294    [ doi:10.1107/S1600536813019351 ]


T. Mohandas, R. Sathishkumar, J. Jayabharathi, A. Pasupathi and P. Sakthivel

Abstract: In the title compound, C29H19F3N2O, a phenanthroline-fused imidazole tetra­cyclic system, the fused benzene rings deviate slightly from the central ring and make dihedral angles with this ring of 3.47 (8) and 3.05 (8)°. The tri­fluoro­methyl­phenyl ring is roughly coplanar with the phenanthroline-fused imidazole tetra­cyclic system [dihedral angle = 11.02 (6)°], while the meth­oxy­phenyl ring is almost perpendicular [dihedral angle = 87.65 (6)°]. There are intra­molecular C-H ...[pi] inter­actions involving the meth­oxy­phenyl ring and the central phenanthroline ring, as well as an inter­molecular C-H...[pi] inter­action involving the phenanthroline ring. In addition, there is an inter­molecular [pi]-[pi] inter­action involving the central phenanthroline ring and the tri­fluoro­methyl­phenyl ring [centroid-centroid distance = 3.685 (2) Å], as well as C-H...N inter­actions linking the mol­ecules into dimers.

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