Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 8 (August 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m430    [ doi:10.1107/S1600536813016139 ]


Y. Zhong, J. Yang and L. Hu

Abstract: In the title compound, [Sm(C7H5O2)3(C12H8N2)], the SmIII cation is coordinated by six O atoms from three bidentate 2-formyl­phenolate ligands and by two N atoms from 1,10-phenanthroline ligand. The resulting SmN2O6 coordination polyhedron is a distorted square anti­prism. In the crystal, C-H...O inter­actions connect mol­ecules into chains along the b-axis direction. In addition, [pi]-[pi] stacking inter­actions are observed with centroid-centroid distances in the range 3.6422 (13)-3.7329 (13) Å.

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