Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 8 (August 2013)

organic compounds

Acta Cryst. (2013). E69, o1255-o1256    [ doi:10.1107/S1600536813018680 ]


M. S. M. Yusof, N. R. Razali, S. Arshad, A. A. Rahman and I. A. Razak

Abstract: The title mol­ecule, C22H17F3N2OS, adopts a trans-cis conformation with respect to the positions of the carbonyl and tri­fluoro­methyl­benzene groups against the thio­carbonyl group across the C-N bonds. The mol­ecular structure is stabilized by an intra­molecular N-H...O hydrogen bond with an S(6) ring motif. The tri­fluoro­methyl-substituted benzene ring forms dihedral angles of 66.05 (9) and 47.19 (9)° with the terminal phenyl rings and is twisted from the O=C-N-(C=S)-N carbonyl­thio­urea plane [maximum deviation = 0.0535 (12) Å], making a dihedral angle of 63.59 (8)°. In the crystal, N-H...O and C-H...F hydrogen bonds link the mol­ecules into a layer parallel to the bc plane. A C-H...[pi] inter­action is also observed.

htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file (82.2 kbytes)
[ doi:10.1107/S1600536813018680/is5283sup0.html ]
Supplementary materials

cmldisplay filedownload file

Chemical Markup Language (CML) file (7.1 kbytes)
[ doi:10.1107/S1600536813018680/is5283Isup3.cml ]
Supplementary material


To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster