Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 8 (August 2013)


metal-organic compounds



is5287 scheme

Acta Cryst. (2013). E69, m443    [ doi:10.1107/S1600536813018394 ]

Bis[2-(1,3-benzothiazol-2-yl)phenyl-[kappa]2C1,N][1,3-bis(4-bromophenyl)propane-1,3-dionato-[kappa]2O,O']iridium(III)

Y.-I. Kim, S.-J. Yun and S. K. Kang

Abstract: The title complex, [Ir(C15H9Br2O2)(C13H8NS)2], lies about a crystallographic twofold rotation axis passing through the IrIII atom and the central C atom of the bis(bromophenyl)propane-1,3-dionate ligand. The IrIII atom adopts a distorted octahedral geometry coordinated by two N atoms in the axial positions, and two C and two O atoms in the equatorial plane. The dihedral angle between the two thiazole ring systems in the complex is 77.45 (10)°.


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