Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 8 (August 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m443    [ doi:10.1107/S1600536813018394 ]


Y.-I. Kim, S.-J. Yun and S. K. Kang

Abstract: The title complex, [Ir(C15H9Br2O2)(C13H8NS)2], lies about a crystallographic twofold rotation axis passing through the IrIII atom and the central C atom of the bis­(bromo­phen­yl)propane-1,3-dionate ligand. The IrIII atom adopts a distorted octa­hedral geometry coordinated by two N atoms in the axial positions, and two C and two O atoms in the equatorial plane. The dihedral angle between the two thia­zole ring systems in the complex is 77.45 (10)°.

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