Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 8 (August 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m455-m456    [ doi:10.1107/S1600536813018813 ]


A. Mishima, N. Katsuta, M. Furusyou, A. Fuyuhiro and S. Kawata

Abstract: The title dinuclear complex mol­ecule, [Cu2(C13H9N4)2(PF6)2], lies about an inversion center. The CuII atom shows a square-pyramidal coordination geometry with the basal plane formed by four N atoms of the two bis-chelating 3,5-bis­(pyridin-2-yl)pyrazolate ions and with one F atom of the hexa­fluoro­phosphate ion in the apical position. Mol­ecules are stacked in a column along the a axis through C-H...F hydrogen bonds. The columns are further linked by other C-H...F hydrogen bonds, forming a three-dimensional network.

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