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Acta Cryst. (2013). E69, i45-i46  [ doi:10.1107/S1600536813018187 ]

Tetraammine(carbonato-[kappa]2O,O')cobalt(III) perchlorate

S. C. Mohan, S. J. Jenniefer, P. T. Muthiah and K. Jothivenkatachalam

Abstract: In the title complex, [Co(CO3)(NH3)4]ClO4, both the cation and anion lie on a mirror plane. The CoIII ion is coordinated by two NH3 ligands and a chelating carbonato ligand in the equatorial sites and by two NH3 groups in the axial sites, forming a distorted octahedral geometry. In the crystal, N-H...O hydrogen bonds connect the anions and cations, forming a three-dimensional network.


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