Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 8 (August 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m454    [ doi:10.1107/S1600536813018941 ]

Di­aqua­bis­(pyridine-2-carboxyl­ato-[kappa]2N,O)zinc di­methyl­formamide hemisolvate

L. Croitor, D. Chisca, E. B. Coropceanu and M. S. Fonari

Abstract: In the title compound, [Zn(C6H4NO2)2(H2O)2]·0.5C3H7NO, the ZnII ion is coordinated in a distorted octa­hedral N2O4 environment by two N,O-chelating pyridine-2-carboxyl­ate ligands and two cis water mol­ecules. The chelating pyridine-2-carboxyl­ate ligands create two five-membered Zn/N/C/C/O rings, which form a dihedral angle of 86.4 (2)°. In the crystal, O-H...O hydrogen bonds link the complex mol­ecules into a two-dimensional network parallel to (100). The di­methyl­formamide solvent mol­ecule is disordered about a twofold rotation axis.

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