Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 8 (August 2013)

metal-organic compounds

lh5630 scheme

Acta Cryst. (2013). E69, m454    [ doi:10.1107/S1600536813018941 ]

Diaquabis(pyridine-2-carboxylato-[kappa]2N,O)zinc dimethylformamide hemisolvate

L. Croitor, D. Chisca, E. B. Coropceanu and M. S. Fonari

Abstract: In the title compound, [Zn(C6H4NO2)2(H2O)2]·0.5C3H7NO, the ZnII ion is coordinated in a distorted octahedral N2O4 environment by two N,O-chelating pyridine-2-carboxylate ligands and two cis water molecules. The chelating pyridine-2-carboxylate ligands create two five-membered Zn/N/C/C/O rings, which form a dihedral angle of 86.4 (2)°. In the crystal, O-H...O hydrogen bonds link the complex molecules into a two-dimensional network parallel to (100). The dimethylformamide solvent molecule is disordered about a twofold rotation axis.

htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file
[ doi:10.1107/S1600536813018941/lh5630sup0.html ]
Supplementary materials


To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster