Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 8 (August 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m471    [ doi:10.1107/S1600536813019338 ]

[5,10,15,20-Tetra­kis(4-meth­oxy­phen­yl)porphyrinato]zinc di­chloro­methane disolvate

S. McGill, V. N. Nesterov and S. L. Gould

Abstract: In the title compound, [Zn(C48H36N4O4)]·2CH2Cl2, the ZnII ion lies on an inversion center and is coordinated in an almost ideal square-planar geometry. The asymmetric unit also contains one di­chloro­methane solvent mol­ecule. The unique meth­oxy-substituted benzene rings form dihedral angles of 59.38 (6) and 66.77 (6)° with the mean plane (r.m.s. deviation of fitted atoms = 0.0282 Å) of the atoms in the porphyrin core. The packing is characterized by close contacts between the ZnII ion and two symmetry-related mol­ecules through the O atoms of a meth­oxy­phenyl group [Zn...O = 2.694 (2) Å], forming a two-dimensional network parallel to (100).

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