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Volume 69 
Part 8 
Page m468  
August 2013  

Received 2 July 2013
Accepted 15 July 2013
Online 20 July 2013

Key indicators
Single-crystal X-ray study
T = 120 K
Mean [sigma](C-C) = 0.003 Å
R = 0.032
wR = 0.092
Data-to-parameter ratio = 13.0
Details
Open access

(Azido-[kappa]N){(E)-2-[1-(pyridin-2-yl)ethylideneamino]phenolato-[kappa]3N,N',O}copper(II)

aDepartment of Chemistry, National Changhua University of Education, Changhua 50058, Taiwan,bSchool of Chemistry and Molecular Biosciences, University of Queensland, Brisbane St Lucia, Queensland 4072, Australia, and cDepartment of Occupational Health and Safety, Chang Jung Christian University, Tainan City 71101, Taiwan
Correspondence e-mail: scschem@mail.cjcu.edu.tw

In the title complex, [Cu(C13H11N2O)(N3)], the CuII cation is four-coordinated by an N2O donor set of the tridentate Schiff base ligand and by the terminal N atom of the azide anion, forming a slightly distorted square-planar configuration.

Related literature

For related structures, see: Talukder et al. (2004[Talukder, P., Datta, A., Mitra, S. & Rosair, G. (2004). Z. Naturforsch. Teil B, 59, 655-660.]); Sun (2008[Sun, X. (2008). Acta Cryst. E64, m33.]); Wang et al. (2012[Wang, H., Lang, Y. & Wang, S. (2012). Acta Cryst. E68, m540.]); Yu (2012[Yu, J. (2012). Acta Cryst. E68, m275.]). For the synthesis, see: Shita et al. (2009[Shita, S., Chakraborty, J., Samanta, B., Rosair, G. M. & Mitra, S. (2009). Z. Naturforsch. Teil B, 64, 403-408.]).

[Scheme 1]

Experimental

Crystal data
  • [Cu(C13H11N2O)(N3)]

  • Mr = 316.81

  • Monoclinic, P 21 /c

  • a = 6.5881 (3) Å

  • b = 10.1576 (3) Å

  • c = 18.3884 (7) Å

  • [beta] = 92.810 (3)°

  • V = 1229.06 (8) Å3

  • Z = 4

  • Cu K[alpha] radiation

  • [mu] = 2.54 mm-1

  • T = 120 K

  • 0.57 × 0.31 × 0.04 mm

Data collection
  • Agilent Xcalibur Gemini ultra diffractometer with Eos detector

  • Absorption correction: multi-scan (CrysAlis PRO; Agilent, 2011)[Agilent (2011). CrysAlis PRO. Agilent Technologies UK Ltd, Yarnton, Oxfordshire, England] Tmin = 0.709, Tmax = 1.000

  • 4723 measured reflections

  • 2357 independent reflections

  • 2180 reflections with I > 2[sigma](I)

  • Rint = 0.021

Refinement
  • R[F2 > 2[sigma](F2)] = 0.032

  • wR(F2) = 0.092

  • S = 1.05

  • 2357 reflections

  • 182 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 0.34 e Å-3

  • [Delta][rho]min = -0.40 e Å-3

Data collection: CrysAlis PRO (Agilent, 2011[Agilent (2011). CrysAlis PRO. Agilent Technologies UK Ltd, Yarnton, Oxfordshire, England]); cell refinement: CrysAlis PRO; data reduction: CrysAlis PRO; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: ORTEP-3 (Farrugia, 2012[Farrugia, L. J. (2012). J. Appl. Cryst. 45, 849-854.]) and WinGX32 (Farrugia, 2012[Farrugia, L. J. (2012). J. Appl. Cryst. 45, 849-854.]); software used to prepare material for publication: publCIF (Westrip, 2010[Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.]).


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: LR2111 ).


Acknowledgements

The authors are grateful to the National Science Council of Taiwan for financial support.

References

Agilent (2011). CrysAlis PRO. Agilent Technologies UK Ltd, Yarnton, Oxfordshire, England
Farrugia, L. J. (2012). J. Appl. Cryst. 45, 849-854.  [Web of Science] [CrossRef] [ChemPort] [IUCr Journals]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [ChemPort] [IUCr Journals]
Shita, S., Chakraborty, J., Samanta, B., Rosair, G. M. & Mitra, S. (2009). Z. Naturforsch. Teil B, 64, 403-408.
Sun, X. (2008). Acta Cryst. E64, m33.  [CSD] [CrossRef] [IUCr Journals]
Talukder, P., Datta, A., Mitra, S. & Rosair, G. (2004). Z. Naturforsch. Teil B, 59, 655-660.  [ChemPort]
Wang, H., Lang, Y. & Wang, S. (2012). Acta Cryst. E68, m540.  [CSD] [CrossRef] [IUCr Journals]
Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.  [Web of Science] [CrossRef] [ChemPort] [IUCr Journals]
Yu, J. (2012). Acta Cryst. E68, m275.  [CSD] [CrossRef] [IUCr Journals]


Acta Cryst (2013). E69, m468  [ doi:10.1107/S1600536813019570 ]

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