Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 8 (August 2013)


metal-organic compounds



ng5336 scheme

Acta Cryst. (2013). E69, m457    [ doi:10.1107/S1600536813019259 ]

Bis{N-benzyl-N-[2-(thiophen-2-yl)ethyl]dithiocarbamato-[kappa]2S,S'}lead(II)

E. Sathiyaraj, S. Thirumaran, B. Sridhar and S. Selvanayagam

Abstract: The molecule of the title compound, [Pb(C14H14NS3)2], is located on a twofold rotation axis. The dithiocarbamate anion S,S'-chelates to the PbII atom, which shows a [Psi]-trigonal-bipyramidal coordination. The thiophene ring is disordered over two positions, the major component having 71.3 (7)% occupancy. The molecular conformation is stabilized by intramolecular C-H...S interactions.


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