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Volume 69 
Part 8 
Pages m448-m449  
August 2013  

Received 8 June 2013
Accepted 3 July 2013
Online 10 July 2013

Key indicators
Single-crystal X-ray study
T = 120 K
Mean [sigma](C-C) = 0.005 Å
Disorder in solvent or counterion
R = 0.075
wR = 0.160
Data-to-parameter ratio = 36.3
Details
Open access

(2,2'-Bipyridine-[kappa]2N,N')tetrakis(dimethyl sulfoxide-[kappa]O)copper(II) bis(perchlorate)

aDepartment of Chemistry, National Taras, Shevchenko University, Volodymyrska, Str. 64, 01601 Kyiv, Ukraine
Correspondence e-mail: tiskenderov@ukr.net

The title compound, [Cu(C2H6OS)4(C10H8N2)](ClO4)2, contains a CuII ion with a distorted octahedral coordination environment, bonded by four O atoms of the monodentate dimethyl sulfoxide ligands and two N atoms of the bidentate chelating 2,2'-bipyridine ligand. The equatorial Cu-N and Cu-O bond lengths are in the range 1.979 (2)-1.998 (3) Å. The axial Cu-O bond distances are 2.365 (2) and 2.394 (2) Å. In the crystal, the complex cations and perchlorate anions are connected by numerous C-H...O hydrogen bonds, which leads to additional stabilization of the structure. The perchlorate anion is disordered over two sets of sites with a 0.716 (3):0.284 (3) occupancy ratio.

Related literature

For applications of the 2,2'-bipyridyl ligand, see: Fritsky et al. (2004[Fritsky, I. O., Swiatek-Kozlowska, J., Dobosz, A., Sliva, T. Yu. & Dudarenko, N. M. (2004). Inorg. Chim. Acta, 357, 3746-3752.], 2006[Fritsky, I. O., Kozlowski, H., Kanderal, O. M., Haukka, M., Swiatek-Kozlowska, J., Gumienna-Kontecka, E. & Meyer, F. (2006). Chem. Commun. pp. 4125-4127.]); Kanderal et al. (2005[Kanderal, O. M., Kozlowski, H., Dobosz, A., Swiatek-Kozlowska, J., Meyer, F. & Fritsky, I. O. (2005). Dalton Trans. pp. 1428-1437.]). For related structures, see: Fritsky et al. (1998[Fritsky, I. O., Kozlowski, H., Sadler, P. J., Yefetova, O. P., Swiatek-Kozlowska, J., Kalibabchuk, V. A. & Glowiak, T. (1998). J. Chem. Soc. Dalton Trans. pp. 3269-3274.], 2000[Fritsky, I. O., Ott, R. & Krämer, R. (2000). Angew. Chem. Int. Ed. 39, 3255-3258.]); Moroz et al. (2010[Moroz, Y. S., Szyrweil, L., Demeshko, S., Kozlowski, H., Meyer, F. & Fritsky, I. O. (2010). Inorg. Chem. 49, 4750-4752.], 2012[Moroz, Y. S., Demeshko, S., Haukka, M., Mokhir, A., Mitra, U., Stocker, M., Müller, P., Meyer, F. & Fritsky, I. O. (2012). Inorg. Chem. 51, 7445-7447.]); Sliva et al. (1997[Sliva, T. Yu., Kowalik-Jankowska, T., Amirkhanov, V. M., Glowiak, T., Onindo, C. O., Fritsky, I. O. & Kozlowski, H. (1997). J. Inorg. Biochem. 65, 287-294.]); Swiatek-Kozlowska et al. (2000[Swiatek-Kozlowska, J., Fritsky, I. O., Dobosz, A., Karaczyn, A., Dudarenko, N. M., Sliva, T. Yu., Gumienna-Kontecka, E. & Jerzykiewicz, L. (2000). J. Chem. Soc. Dalton Trans. pp. 4064-4068.], 2002[Swiatek-Kozlowska, J., Gumienna-Kontecka, E., Dobosz, A., Golenya, I. A. & Fritsky, I. O. (2002). J. Chem. Soc. Dalton Trans. pp. 4639-4643.]); Iskenderov et al. (2009[Iskenderov, T. S., Golenya, I. A., Gumienna-Kontecka, E., Fritsky, I. O. & Prisyazhnaya, E. V. (2009). Acta Cryst. E65, o2123-o2124.]); Golenya et al. (2012a[Golenya, I. A., Gumienna-Kontecka, E., Boyko, A. N., Haukka, M. & Fritsky, I. O. (2012a). Dalton Trans. 41, 9427-9430.]). For the synthesis, see: Golenya et al. (2012b[Golenya, I. A., Gumienna-Kontecka, E., Boyko, A. N., Haukka, M. & Fritsky, I. O. (2012b). Inorg. Chem. 51, 6221-6227.]).

[Scheme 1]

Experimental

Crystal data
  • [Cu(C2H6OS)4(C10H8N2)](ClO4)2

  • Mr = 731.14

  • Monoclinic, P 21 /n

  • a = 10.8050 (5) Å

  • b = 11.6470 (5) Å

  • c = 24.5210 (8) Å

  • [beta] = 94.984 (5)°

  • V = 3074.2 (2) Å3

  • Z = 4

  • Mo K[alpha] radiation

  • [mu] = 1.21 mm-1

  • T = 120 K

  • 0.33 × 0.23 × 0.12 mm

Data collection
  • Nonius KappaCCD diffractometer

  • Absorption correction: multi-scan (MULABS; Blessing, 1995[Blessing, R. H. (1995). Acta Cryst. A51, 33-38.]) Tmin = 0.747, Tmax = 0.862

  • 40246 measured reflections

  • 13140 independent reflections

  • 6565 reflections with I > 2[sigma](I)

  • Rint = 0.074

Refinement
  • R[F2 > 2[sigma](F2)] = 0.075

  • wR(F2) = 0.160

  • S = 1.07

  • 13140 reflections

  • 362 parameters

  • 10 restraints

  • H-atom parameters constrained

  • [Delta][rho]max = 1.21 e Å-3

  • [Delta][rho]min = -0.84 e Å-3

Table 1
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
C1-H1...O2 0.95 2.52 3.046 (4) 115
C6-H6...O8i 0.95 2.47 3.255 (5) 140
C8-H8...O3 0.95 2.42 2.946 (4) 115
C4-H4...O1ii 0.95 2.35 3.219 (4) 151
C16-H16B...O5iii 0.98 2.56 3.411 (5) 145
C17-H17B...O5iii 0.98 2.40 3.306 (5) 153
C15-H15C...O7iv 0.98 2.51 3.320 (5) 140
Symmetry codes: (i) -x+1, -y+1, -z; (ii) -x, -y+1, -z; (iii) [x-{\script{1\over 2}}, -y+{\script{1\over 2}}, z+{\script{1\over 2}}]; (iv) -x, -y, -z.

Data collection: COLLECT (Nonius, 2000[Nonius (2000). COLLECT. Nonius BV, Delft, The Netherlands.]); cell refinement: DENZO/SCALEPACK (Otwinowski & Minor, 1997[Otwinowski, Z. & Minor, W. (1997). Methods in Enzymology, Vol. 276, Macromolecular Crystallography, Part A, edited by C. W. Carter & R. M. Sweet, pp. 307-326. New York: Academic Press.]); data reduction: DENZO/SCALEPACK; program(s) used to solve structure: SIR2004 (Burla et al., 2005[Burla, M. C., Caliandro, R., Camalli, M., Carrozzini, B., Cascarano, G. L., De Caro, L., Giacovazzo, C., Polidori, G. & Spagna, R. (2005). J. Appl. Cryst. 38, 381-388.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: DIAMOND (Brandenburg, 2009[Brandenburg, K. (2009). DIAMOND. Crystal Impact GbR, Bonn, Germany.]); software used to prepare material for publication: SHELXL97.


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: NR2046 ).


Acknowledgements

The financial support from the State Fund for Fundamental Researches of Ukraine (grant No. GP/F36/032) is gratefully acknowledged. We also thank Dr E. B. Rusanov, Institute of Organic Chemistry of the National Academy of Sciences of Ukraine, for collecting the X-ray data.

References

Blessing, R. H. (1995). Acta Cryst. A51, 33-38.  [CrossRef] [IUCr Journals]
Brandenburg, K. (2009). DIAMOND. Crystal Impact GbR, Bonn, Germany.
Burla, M. C., Caliandro, R., Camalli, M., Carrozzini, B., Cascarano, G. L., De Caro, L., Giacovazzo, C., Polidori, G. & Spagna, R. (2005). J. Appl. Cryst. 38, 381-388.  [Web of Science] [CrossRef] [ChemPort] [IUCr Journals]
Fritsky, I. O., Kozlowski, H., Kanderal, O. M., Haukka, M., Swiatek-Kozlowska, J., Gumienna-Kontecka, E. & Meyer, F. (2006). Chem. Commun. pp. 4125-4127.  [CSD] [CrossRef]
Fritsky, I. O., Kozlowski, H., Sadler, P. J., Yefetova, O. P., Swiatek-Kozlowska, J., Kalibabchuk, V. A. & Glowiak, T. (1998). J. Chem. Soc. Dalton Trans. pp. 3269-3274.  [CSD] [CrossRef]
Fritsky, I. O., Ott, R. & Krämer, R. (2000). Angew. Chem. Int. Ed. 39, 3255-3258.  [ChemPort]
Fritsky, I. O., Swiatek-Kozlowska, J., Dobosz, A., Sliva, T. Yu. & Dudarenko, N. M. (2004). Inorg. Chim. Acta, 357, 3746-3752.  [Web of Science] [CSD] [CrossRef] [ChemPort]
Golenya, I. A., Gumienna-Kontecka, E., Boyko, A. N., Haukka, M. & Fritsky, I. O. (2012a). Dalton Trans. 41, 9427-9430.  [CSD] [CrossRef] [ChemPort] [PubMed]
Golenya, I. A., Gumienna-Kontecka, E., Boyko, A. N., Haukka, M. & Fritsky, I. O. (2012b). Inorg. Chem. 51, 6221-6227.  [Web of Science] [CSD] [CrossRef] [ChemPort] [PubMed]
Iskenderov, T. S., Golenya, I. A., Gumienna-Kontecka, E., Fritsky, I. O. & Prisyazhnaya, E. V. (2009). Acta Cryst. E65, o2123-o2124.  [CSD] [CrossRef] [ChemPort] [IUCr Journals]
Kanderal, O. M., Kozlowski, H., Dobosz, A., Swiatek-Kozlowska, J., Meyer, F. & Fritsky, I. O. (2005). Dalton Trans. pp. 1428-1437.  [CrossRef] [PubMed]
Moroz, Y. S., Demeshko, S., Haukka, M., Mokhir, A., Mitra, U., Stocker, M., Müller, P., Meyer, F. & Fritsky, I. O. (2012). Inorg. Chem. 51, 7445-7447.  [Web of Science] [CSD] [CrossRef] [ChemPort] [PubMed]
Moroz, Y. S., Szyrweil, L., Demeshko, S., Kozlowski, H., Meyer, F. & Fritsky, I. O. (2010). Inorg. Chem. 49, 4750-4752.  [Web of Science] [CSD] [CrossRef] [ChemPort] [PubMed]
Nonius (2000). COLLECT. Nonius BV, Delft, The Netherlands.
Otwinowski, Z. & Minor, W. (1997). Methods in Enzymology, Vol. 276, Macromolecular Crystallography, Part A, edited by C. W. Carter & R. M. Sweet, pp. 307-326. New York: Academic Press.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [ChemPort] [IUCr Journals]
Sliva, T. Yu., Kowalik-Jankowska, T., Amirkhanov, V. M., Glowiak, T., Onindo, C. O., Fritsky, I. O. & Kozlowski, H. (1997). J. Inorg. Biochem. 65, 287-294.  [CrossRef] [ChemPort] [Web of Science]
Swiatek-Kozlowska, J., Fritsky, I. O., Dobosz, A., Karaczyn, A., Dudarenko, N. M., Sliva, T. Yu., Gumienna-Kontecka, E. & Jerzykiewicz, L. (2000). J. Chem. Soc. Dalton Trans. pp. 4064-4068.
Swiatek-Kozlowska, J., Gumienna-Kontecka, E., Dobosz, A., Golenya, I. A. & Fritsky, I. O. (2002). J. Chem. Soc. Dalton Trans. pp. 4639-4643.


Acta Cryst (2013). E69, m448-m449   [ doi:10.1107/S1600536813018485 ]

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