Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 8 (August 2013)


metal-organic compounds



rz5076 scheme

Acta Cryst. (2013). E69, m437    [ doi:10.1107/S1600536813018102 ]

catena-Poly[heptylenediammonium [[tetrachloridobismuthate(III)]-[mu]-chlorido]]

A. Ouasri, A. Rhandour, M. Saadi and L. El Ammari

Abstract: The title organic-inorganic hybrid compound, {(C7H20N2)[BiCl5]}n, consists of distorted corner-joined [BiCl6] octahedra forming zigzag polymeric anionic chains parallel to [001], separated by columns of heptylenediammonium cations. The asymmetric unit contains two crystallographically independent bismuth metal atoms, one of which lies on an inversion centre and the other on a twofold axis. In the crystal, the polymeric chains and cations are linked by N-H...Cl hydrogen bonds, forming undulating layers parallel to (110).


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