Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 8 (August 2013)


metal-organic compounds



sj5326 scheme

Acta Cryst. (2013). E69, m426    [ doi:10.1107/S1600536813015845 ]

Poly[[mu]-aqua-[mu]-(N,4-dichloro-2-methylbenzenesulfonamidato)-potassium]

H. S. Spandana, S. Foro and B. T. Gowda

Abstract: In the title compound, [K(C7H6Cl2NO2S)(H2O)]n, the K+ cation is heptacoordinated by two water O atoms, a sulfonyl O atom from each of four different N,4-dichloro-2-methylbenzenesulfonamidate anions and a Cl atom of one of the anions. Further, K-O-K bridges form extensive polymeric chains along the b axis. In the crystal structure, the anions are linked into layers parallel to (100) by O-H...Cl and O-H...N hydrogen bonds.


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