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Acta Cryst. (2013). E69, m446-m447  [ doi:10.1107/S1600536813017376 ]

Dichloridobis[3-(4-chlorophenyl)-2,N,N-trimethyl-2,3-dihydro-1,2,4-oxadiazole-5-amine-[kappa]N4]platinum(II)-4-chlorobenzaldehyde (1/1)

A. S. Kritchenkov, V. V. Gurzhiy, N. A. Bokach and V. A. Kalibabchuk

Abstract: In the title 1:1 co-crystal, [PtCl2(C11H14ClN3O)2]·C7H5ClO, the coordination polyhedron of the PtII atom is slightly distorted square-planar with the chloride and 2,3-dihydro-1,2,4-oxadiazole ligands mutually trans, as the Pt atom lies on an inversion center. The 4-chlorobenzaldehyde molecules are statistically disordered about an inversion centre with equal occupancies for the two positions. The PtII complex forms a three-dimensional structure through C-H...Cl and weaker C-H...O interactions with the 4-chlorobenzaldehyde molecule.


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