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Volume 69 
Part 8 
Page m427  
August 2013  

Received 19 June 2013
Accepted 26 June 2013
Online 3 July 2013

Key indicators
Single-crystal X-ray study
T = 100 K
Mean [sigma](C-C) = 0.003 Å
R = 0.024
wR = 0.061
Data-to-parameter ratio = 11.8
Details
Open access

catena-Poly[[triphenyltin(IV)]-[mu]-N-(4-acetylphenyl)maleamato]

aDepartment of Chemistry, Allama Iqbal Open University, Islamabad, Pakistan, and bSchool of Chemistry, University of Manchester, Manchester M30 9PL, England
Correspondence e-mail: moazzamhussain_b@yahoo.com

The crystal structure of the polymeric title compound, [Sn(C6H5)3(C12H10NO4)]n, comprises polymeric chains whereby adjacent Sn atoms are bridged by carboxylate and amide carbonyl O atoms [Sn-O = 2.115 (15) and 2.653 (1) Å, respectively]. The SnIV atom is five-coordinated showing a distorted trigonal-bipyramid geometry, with the three phenyl ipso-C atoms defining the trigonal plane and the axial positions occupied by O atoms [O-Sn-O = 171.91 (5)°]. Intramolecular N-H...O hydrogen bonding leads to a seven-membered loop. There is an intramolecular C-H...O interaction within the polymeric chain. An intermolecular C-H...O interaction along c links the polymeric chains into sheets which are linked into a three-dimensional network via C-H...[pi] interactions.

Related literature

For reviews of organotin structural chemistry, see: Tiekink (1991[Tiekink, E. R. T. (1991). Appl. Organomet. Chem. 5, 1-23.], 1994[Tiekink, E. R. T. (1994). Trends Organomet. Chem. 1, 71-116.]). For related structures, see: Sadiq-ur-Rehman et al. (2005[Sadiq-ur-Rehman, Shahid, K, Ali, S., Bhatti, M.H. & Parvez, M., (2005). J. Organomet. Chem. 690, 1396-1408.]); Parvez et al. (2002[Parvez, M., Ali, S., Ahmad, S., Bhatti, M. H. & Mazhar, M. (2002). Acta Cryst. C58, m334-m335.]).

[Scheme 1]

Experimental

Crystal data
  • [Sn(C6H5)3(C12H10NO4)]

  • Mr = 582.20

  • Triclinic, [P \overline 1]

  • a = 9.7556 (5) Å

  • b = 11.3298 (6) Å

  • c = 12.0571 (6) Å

  • [alpha] = 73.187 (1)°

  • [beta] = 87.082 (1)°

  • [gamma] = 79.841 (1)°

  • V = 1255.69 (11) Å3

  • Z = 2

  • Mo K[alpha] radiation

  • [mu] = 1.05 mm-1

  • T = 100 K

  • 0.40 × 0.30 × 0.30 mm

Data collection
  • Bruker SMART CCD area-detector diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2001[Bruker (2001). SMART and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.726, Tmax = 1.000

  • 10025 measured reflections

  • 5034 independent reflections

  • 4905 reflections with I > 2[sigma](I)

  • Rint = 0.017

Refinement
  • R[F2 > 2[sigma](F2)] = 0.024

  • wR(F2) = 0.061

  • S = 1.09

  • 5034 reflections

  • 425 parameters

  • All H-atom parameters refined

  • [Delta][rho]max = 0.94 e Å-3

  • [Delta][rho]min = -0.52 e Å-3

Table 1
Hydrogen-bond geometry (Å, °)

Cg1-Cg3 are the centroids of the C1-C6, C7-C12 and C13-C18 benzene rings, respectively.

D-H...A D-H H...A D...A D-H...A
N1-H1N...O2 0.87 (3) 1.88 (3) 2.707 (2) 158 (2)
C6-H6...O3i 0.91 (3) 2.58 (3) 3.253 (3) 131 (2)
C20-H20...O4ii 0.93 (3) 2.48 (3) 3.242 (3) 139 (2)
C3-H3...Cg2iii 0.92 (3) 2.93 (3) 3.651 (2) 137 (2)
C27-H27...Cg3iv 0.92 (3) 2.83 (3) 3.674 (2) 154 (2)
C30-H30C...Cg1v 0.93 (3) 2.93 (3) 3.794 (4) 155 (3)
Symmetry codes: (i) x+1, y, z; (ii) x, y, z+1; (iii) -x+2, -y, -z+1; (iv) -x+2, -y+1, -z; (v) x-1, y, z-1.

Data collection: SMART (Bruker, 2001[Bruker (2001). SMART and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2002[Bruker (2002). SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]) and PLATON (Spek, 2009[Spek, A. L. (2009). Acta Cryst. D65, 148-155.]); software used to prepare material for publication: SHELXTL.


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: TK5234 ).


Acknowledgements

The authors gratefully acknowledge Allama Iqbal Open University, Islamabad, Pakistan, for providing research facilities.

References

Bruker (2001). SMART and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Bruker (2002). SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
Parvez, M., Ali, S., Ahmad, S., Bhatti, M. H. & Mazhar, M. (2002). Acta Cryst. C58, m334-m335.  [CSD] [CrossRef] [IUCr Journals]
Sadiq-ur-Rehman, Shahid, K, Ali, S., Bhatti, M.H. & Parvez, M., (2005). J. Organomet. Chem. 690, 1396-1408.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [ChemPort] [IUCr Journals]
Spek, A. L. (2009). Acta Cryst. D65, 148-155.  [Web of Science] [CrossRef] [ChemPort] [IUCr Journals]
Tiekink, E. R. T. (1991). Appl. Organomet. Chem. 5, 1-23.  [CrossRef] [ChemPort] [Web of Science]
Tiekink, E. R. T. (1994). Trends Organomet. Chem. 1, 71-116.


Acta Cryst (2013). E69, m427  [ doi:10.1107/S1600536813017613 ]

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