Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 8 (August 2013)


metal-organic compounds



wm2753 scheme

Acta Cryst. (2013). E69, m472    [ doi:10.1107/S1600536813019806 ]

trans-Bis([mu]-benzenethiolato-[kappa]2S:S)bis[chlorido(triphenylphosphane-[kappa]P)palladium(II)] chloroform disolvate

A. Avila-Sorrosa, A. Reyes-Arellano, J. M. Germán-Acacio, R. Reyes-Martínez and D. Morales-Morales

Abstract: The title compound, [Pd2Cl2(C6H5S)2(C18H15P)2]·2CHCl3, contains a centrosymmetric dinuclear palladium complex with the PdII cation in a slightly distorted square-planar coordination environment. The PdII cations are bridged by the S atoms of two benzenethiolate ligands with different Pd-S distances [2.2970 (11) and 2.3676 (11) Å]. The coordination of the metal atom is completed by a chloride anion [2.3383 (11) Å] and a triphenylphosphane ligand [2.2787 (11) Å]. Weak C-H...Cl interactions are present between complex molecules and the CHCl3 solvent molecule. The latter is disordered over two positions in a 0.792 (8):0.208 (8) ratio. The crystal under investigation was found to be twinned by nonmerohedry, with a fraction of 73.4 (1)% for the major twin component.


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