Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 8 (August 2013)


metal-organic compounds



xu5715 scheme

Acta Cryst. (2013). E69, m435-m436    [ doi:10.1107/S1600536813018059 ]

Dichloridobis[3-(4-methoxyphenyl)-2-methyl-5-(piperidin-1-yl)-2,3-dihydro-1,2,4-oxadiazole-[kappa]N4]platinum(II)

A. S. Kritchenkov, L. V. Lavnevich, G. L. Starova, N. A. Bokach and V. A. Kalibabchuk

Abstract: In title compound, [PtCl2(C15H21N3O2)2], the PtII cation, located on an inversion center, is coordinated by two Cl- anions and two 3-(4-methoxyphenyl)-2-methyl-5-(piperidin-1-yl)-2,3-dihydro-1,2,4-oxadiazole ligands in a distorted Cl2N2 square-planar geometry. The dihydrooxadiazole and piperidine rings display envelope (with the non-coordinating N atom as the flap atom) and chair conformations, respectively. In the crystal, weak C-H...Cl hydrogen bonds link the molecules into supramolecular chains running along the b axis. The piperidine ring is disordered over two positions with the occupancy ratio of 0.528 (4):0.472 (4).


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