Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 8 (August 2013)


metal-organic compounds



xu5717 scheme

Acta Cryst. (2013). E69, m439-m440    [ doi:10.1107/S1600536813018321 ]

Diaquabis[2-(2-hydroxyethyl)pyridine-[kappa]2N,O]cobalt(II) dichloride

O. Zeghouan, F. Guenifa, N. Hadjadj, L. Bendjeddou and H. Merazig

Abstract: In the title salt, [Co(C7H9NO)2(H2O)2]Cl2, the CoII cation, located on an inversion center, is N,O-chelated by two hydroxyethylpyridine ligands and coordinated by two water molecules in a distorted O4N2 octahedral geometry. In the crystal, the Cl- anions link with the complex cations via O-H...Cl hydrogen bonds, forming a three-dimensional supramolecular architecture. [pi]-[pi] stacking is observed between the pyridine rings of adjacent molecules [centroid-centroid distance = 3.5810 (11) Å].


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