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Volume 69 
Part 9 
Page m523  
September 2013  

Received 17 August 2013
Accepted 28 August 2013
Online 31 August 2013

Key indicators
Single-crystal X-ray study
T = 296 K
Mean [sigma](C-C) = 0.004 Å
R = 0.029
wR = 0.073
Data-to-parameter ratio = 11.8
Details
Open access

catena-Poly[{[mu]-N'-[2-(carboxylatomethoxy)benzylidene]-2-hydroxybenzohydrazidato}(methanol-[kappa]O)nickel(II)]

aDepartment of Chemistry and Chemical Engineering, Sichuan University of Arts and Science, Sichuan Key Laboratory of Characteristic Plant Development Research, Dazhou, Sichuan 635000, People's Republic of China, and bDepartment of Chemistry and Chemical Engineering, Sichuan University of Arts and Science, Dazhou, Sichuan 635000, People's Republic of China
Correspondence e-mail: fhluo2005@163.com

In the title compound, [Ni(C16H12N2O5)(CH3OH)]n, the unique NiII ion is coordinated in a distorted octahedral environment by three O atoms and one N atom from a symmetry-unique ligand in the equatorial sites. Coordination of the axial sites is provided by an O atom of a symmetry-unique methanol ligand and an O atom of a carboxylate group from a symmetry-related ligand, thus generating a one-dimensional polymer parallel to [010]. In the crystal, O-H...N hydrogen bonds and [pi]-[pi] interactions, with a centroid-centroid distance of 3.693 (2) Å, form a two-dimensional network parallel to (100). In addition, weak C-H...O and C-H...N hydrogen bonds complete a three-dimensional network. An intramolecular O-H...O hydrogen bond is also observed.

Related literature

For background information on nickel(II) carboxylate compounds, see: Lu et al. (2010[Lu, R. Q., Chen, Y. Y. & Zhou, H. (2010). Acta Chim. Sin. 68, 1199-1204.]). For general information on the structures of carboxylate and hydrazone compounds, see: Wu et al. (2007[Wu, L. M., Qiu, G. F. & Teng, H. B. (2007). Inorg. Chim. Acta, 360, 3069-3074.]); Luo et al. (2010[Luo, F. H., Hu, Z. Q. & Yang, L. (2010). Chin. J. Inorg. Chem. 26, 682-686.]).

[Scheme 1]

Experimental

Crystal data
  • [Ni(C16H12N2O5)(CH4O)]

  • Mr = 403.03

  • Monoclinic, P 21 /c

  • a = 10.0877 (14) Å

  • b = 8.1922 (10) Å

  • c = 20.570 (2) Å

  • [beta] = 102.589 (8)°

  • V = 1659.0 (4) Å3

  • Z = 4

  • Mo K[alpha] radiation

  • [mu] = 1.21 mm-1

  • T = 296 K

  • 0.20 × 0.20 × 0.15 mm

Data collection
  • Bruker SMART CCD diffractometer

  • 12305 measured reflections

  • 2921 independent reflections

  • 2635 reflections with I > 2[sigma](I)

  • Rint = 0.027

Refinement
  • R[F2 > 2[sigma](F2)] = 0.029

  • wR(F2) = 0.073

  • S = 1.08

  • 2921 reflections

  • 248 parameters

  • H atoms treated by a mixture of independent and constrained refinement

  • [Delta][rho]max = 0.35 e Å-3

  • [Delta][rho]min = -0.24 e Å-3

Table 1
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
C7-H7...O6i 0.93 2.46 3.350 (3) 160
C3-H3B...O1ii 0.97 2.36 3.151 (3) 138
O5-H2M...N6iii 0.77 (3) 1.95 (3) 2.721 (2) 172 (3)
O6-H2A...O4 0.99 (4) 1.63 (4) 2.547 (3) 151 (4)
Symmetry codes: (i) x-1, y, z; (ii) [-x+1, y-{\script{1\over 2}}, -z+{\script{1\over 2}}]; (iii) -x+1, -y+1, -z+1.

Data collection: SMART (Bruker, 2001[Bruker (2001). SMART and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2001[Bruker (2001). SMART and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: PLATON (Spek, 2009[Spek, A. L. (2009). Acta Cryst. D65, 148-155.]); software used to prepare material for publication: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]).


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: LH5646 ).


Acknowledgements

We are grateful to the Youth Foundation of the Education Department of Sichuan Province (grant Nos. 12ZA282 and 12ZA146).

References

Bruker (2001). SMART and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
Lu, R. Q., Chen, Y. Y. & Zhou, H. (2010). Acta Chim. Sin. 68, 1199-1204.  [ChemPort]
Luo, F. H., Hu, Z. Q. & Yang, L. (2010). Chin. J. Inorg. Chem. 26, 682-686.  [ChemPort]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [ChemPort] [details]
Spek, A. L. (2009). Acta Cryst. D65, 148-155.  [ISI] [CrossRef] [ChemPort] [details]
Wu, L. M., Qiu, G. F. & Teng, H. B. (2007). Inorg. Chim. Acta, 360, 3069-3074.  [ISI] [CSD] [CrossRef] [ChemPort]


Acta Cryst (2013). E69, m523  [ doi:10.1107/S1600536813024161 ]

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