Received 17 August 2013
aDepartment of Chemistry and Chemical Engineering, Sichuan University of Arts and Science, Sichuan Key Laboratory of Characteristic Plant Development Research, Dazhou, Sichuan 635000, People's Republic of China, and bDepartment of Chemistry and Chemical Engineering, Sichuan University of Arts and Science, Dazhou, Sichuan 635000, People's Republic of China
Correspondence e-mail: email@example.com
In the title compound, [Ni(C16H12N2O5)(CH3OH)]n, the unique NiII ion is coordinated in a distorted octahedral environment by three O atoms and one N atom from a symmetry-unique ligand in the equatorial sites. Coordination of the axial sites is provided by an O atom of a symmetry-unique methanol ligand and an O atom of a carboxylate group from a symmetry-related ligand, thus generating a one-dimensional polymer parallel to . In the crystal, O-HN hydrogen bonds and - interactions, with a centroid-centroid distance of 3.693 (2) Å, form a two-dimensional network parallel to (100). In addition, weak C-HO and C-HN hydrogen bonds complete a three-dimensional network. An intramolecular O-HO hydrogen bond is also observed.
For background information on nickel(II) carboxylate compounds, see: Lu et al. (2010). For general information on the structures of carboxylate and hydrazone compounds, see: Wu et al. (2007); Luo et al. (2010).
Data collection: SMART (Bruker, 2001); cell refinement: SAINT (Bruker, 2001); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: PLATON (Spek, 2009); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: LH5646 ).
We are grateful to the Youth Foundation of the Education Department of Sichuan Province (grant Nos. 12ZA282 and 12ZA146).
Bruker (2001). SMART and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
Lu, R. Q., Chen, Y. Y. & Zhou, H. (2010). Acta Chim. Sin. 68, 1199-1204.
Luo, F. H., Hu, Z. Q. & Yang, L. (2010). Chin. J. Inorg. Chem. 26, 682-686.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.
Spek, A. L. (2009). Acta Cryst. D65, 148-155.
Wu, L. M., Qiu, G. F. & Teng, H. B. (2007). Inorg. Chim. Acta, 360, 3069-3074.