Received 28 August 2013
In the title compound C13H10ClN3O3S, the benzoyl group maintains its trans conformation against the thiono group about the C-N bond and the intramolecular hydrogen bond between the benzoyl O atom and thioamide H atom. In the crystal, N-HO and C-HO hydrogen bonds link the molecules, forming chains along the b-axis direction. In addition, C-H interactions occur between a phenyl H atom and the furan ring.
For bond-lengths data, see: Allen et al. (1987) and for a description of the Cambridge Structural Database, see: Allen (2002). For related structures of thiourea derivatives, see: Yamin & Yusof (2003); Yusof et al. (2003); Ali et al. (2004); Venkatachalam et al. (2004); Saeed et al. (2011); Wilson et al. (2010).
Data collection: SMART (Bruker, 2000); cell refinement: SAINT (Bruker, 2000); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL and PLATON (Spek, 2009).
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: BG2516 ).
The authors would like to thank Universiti Kebangsaan Malaysia and the Ministry of Science and Technology, Malaysia, for research grants FRGS/1/213/ST01/UKM/03/4 and DIP-2012-11 and the Centre of Research and Instrumentation (CRIM) for the research facilities.
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