Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 10 (October 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m528-m529    [ doi:10.1107/S1600536813023040 ]

{2-[1-(2-Meth­oxy-6-oxidophenyl-[kappa]O6)ethyl­idene]-N-methyl­hydrazinecarbo­thio­amidato-[kappa]2N2,S}(tri­phenyl­phosphane-[kappa]P)palladium(II) ethanol monosolvate

B. J. Anderson, K. A. O'Rourke, A. M. Keeler and J. P. Jasinski

Abstract: In the title compound, [Pd(C11H13N3O2S)(C18H15P)]·C2H5OH, the PdII atom is tetra­coordinated in a slightly distorted square-planar environment by three donor atoms (NOS) from a thio­semicarbazonate ligand, forming five- and six-membered chelate rings, and a P atom from a neutral tri­phenyl­phosphane group. The five-membered ring adopts a distorted envelope conformation with PdII as the flap atom, while the six-membered ring forms a slightly twisted screw-boat conformation. A slightly distorted screw-boat form of a meth­oxy­phenyl group is fused to the six-membered ring. Weak C-H...O inter­actions form dimers in the asymmetric unit and along [001] which help to stabilize the crystal packing.

htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file (97.4 kbytes)
[ doi:10.1107/S1600536813023040/bv2224sup0.html ]
Supplementary materials


To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster