Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 10 (October 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m542-m543    [ doi:10.1107/S1600536813024768 ]


M. G. Meera, P. K. Selvaraj, B. Viswanathan and V. Ramkumar

Abstract: In the title compound, [Cu2(C19H31N4O)(OH)(NCS)2], the mol­ecular structure of the dinuclear complex reveals two penta­coordinated CuII ions, which are bridged by the phenolate O atom of the ligand and by an exogenous hydroxide ion. The bridging atoms occupy equatorial positions in the coordination sphere of the metal atoms and complete the equatorial coordination planes with two ligand N atoms, the apical positions being occupied by thio­cyanate N atoms. The crystal structure also features [pi]-[pi] stacking inter­actions involving the benzene rings with a centroid-centroid distance of 3.764 (4)Å. The crystal studied was a non-merohedral twin, with a refined BASF value of 0.203 (2)

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