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Acta Cryst. (2013). E69, m567
[ doi:10.1107/S1600536813026135 ]

Pyridinium trans-diaquabis[oxalato(2-)-[kappa]2O1,O2]chromate(III) urea monosolvate

G. Bebga, M. Signé, J. Nenwa, M. Mbarki and B. P. T. Fokwa

Abstract: The asymmetric unit of the title solvated molecular salt, (C5H6N)[Cr(C2O4)2(H2O)2]·CO(NH2)2, contains half a formula unit. Each component is completed by crystallographic twofold symmetry: in the cation, one C and the N atom lie on the rotation axis; in the anion, the CrIII ion lies on the axis; in the solvent molecule, the C and the O atom lie on the axis. The aqua ligands are in a trans disposition in the resulting CrO6 octahedron. In the crystal, the components are linked by O-H...O, N-H...O and N-H...(O,O) hydrogen bonds, generating a three-dimensional network.


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