[Journal logo]

Volume 69 
Part 10 
Page m525  
October 2013  

Received 20 August 2013
Accepted 27 August 2013
Online 4 September 2013

Key indicators
Single-crystal X-ray study
T = 296 K
Mean [sigma](C-C) = 0.008 Å
R = 0.039
wR = 0.113
Data-to-parameter ratio = 13.4
Details
Open access

Bis[[mu]-1-(3,5-dichloropyridin-2-yl)-2-(pyridin-3-ylmethylidene)hydrazine]bis[(nitrato-[kappa]O)silver(I)] acetonitrile disolvate

aCollege of Science, Civil Aviation University of China, Tianjin 300300, People's Repulic of China
Correspondence e-mail: caihua-1109@163.com

In the centrosymmetric binuclear title complex, [Ag2(NO3)2(C11H8Cl2N4)2]·2CH3CN, the AgI atom is four-coordinated and exhibits a highly distorted tetrahedral coordination sphere defined by three N atoms from two 1-(3,5-dichloropyridin-2-yl)-2-(pyridin-3-ylmethylidene)hydrazine ligands and one O atom from a nitrate anion. Intermolecular N-H...O hydrogen bonds link the complex molecules, resulting in a two-dimensional supramolecular structure parallel to (001).

Related literature

For background to compounds with metal-organic framework structures, see: Barnett & Champness (2003[Barnett, S. A. & Champness, N. R. (2003). Coord. Chem. Rev. 246, 145-168.]); Roesky & Andruh (2003[Roesky, H. W. & Andruh, M. (2003). Coord. Chem. Rev. 236, 91-119.]); Zaworotko (2000[Zaworotko, M. J. (2000). Chem. Commun. pp. 1-9.]).

[Scheme 1]

Experimental

Crystal data
  • [Ag2(NO3)2(C11H8Cl2N4)2]·2C2H3N

  • Mr = 956.10

  • Orthorhombic, P b c a

  • a = 15.3862 (19) Å

  • b = 8.2397 (10) Å

  • c = 27.198 (4) Å

  • V = 3448.1 (8) Å3

  • Z = 4

  • Mo K[alpha] radiation

  • [mu] = 1.51 mm-1

  • T = 296 K

  • 0.32 × 0.28 × 0.22 mm

Data collection
  • Bruker APEXII CCD diffractometer

  • Absorption correction: multi-scan (SADABS; Sheldrick, 1996[Sheldrick, G. M. (1996). SADABS. University of Göttingen, Germany.]) Tmin = 0.645, Tmax = 0.733

  • 16325 measured reflections

  • 3041 independent reflections

  • 2498 reflections with I > 2[sigma](I)

  • Rint = 0.029

Refinement
  • R[F2 > 2[sigma](F2)] = 0.039

  • wR(F2) = 0.113

  • S = 1.08

  • 3041 reflections

  • 227 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 0.66 e Å-3

  • [Delta][rho]min = -0.50 e Å-3

Table 1
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
N2-H2...O3i 0.86 2.09 2.909 (5) 158
Symmetry code: (i) [x+{\script{1\over 2}}, -y+{\script{3\over 2}}, -z+1].

Data collection: APEX2 (Bruker, 2007[Bruker (2007). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2007[Bruker (2007). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: XP in SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]) and DIAMOND (Brandenburg & Berndt, 1999[Brandenburg, K. & Berndt, M. (1999). DIAMOND. Crystal Impact GbR, Bonn, Germany.]); software used to prepare material for publication: SHELXTL.


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: HY2636 ).


References

Barnett, S. A. & Champness, N. R. (2003). Coord. Chem. Rev. 246, 145-168.  [Web of Science] [CrossRef] [ChemPort]
Brandenburg, K. & Berndt, M. (1999). DIAMOND. Crystal Impact GbR, Bonn, Germany.
Bruker (2007). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
Roesky, H. W. & Andruh, M. (2003). Coord. Chem. Rev. 236, 91-119.  [Web of Science] [CrossRef] [ChemPort]
Sheldrick, G. M. (1996). SADABS. University of Göttingen, Germany.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [ChemPort] [IUCr Journals]
Zaworotko, M. J. (2000). Chem. Commun. pp. 1-9.


Acta Cryst (2013). E69, m525  [ doi:10.1107/S1600536813024021 ]

This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.