Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 10 (October 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m525    [ doi:10.1107/S1600536813024021 ]

Bis[[mu]-1-(3,5-di­chloro­pyridin-2-yl)-2-(pyridin-3-yl­methyl­idene)hydrazine]bis­[(nitrato-[kappa]O)silver(I)] aceto­nitrile disolvate

Y. Guo and H. Cai

Abstract: In the centrosymmetric binuclear title complex, [Ag2(NO3)2(C11H8Cl2N4)2]·2CH3CN, the AgI atom is four-coordinated and exhibits a highly distorted tetrahedral coordination sphere defined by three N atoms from two 1-(3,5-di­chloro­pyridin-2-yl)-2-(pyridin-3-yl­methyl­idene)hy­drazine ligands and one O atom from a nitrate anion. Inter­molecular N-H...O hydrogen bonds link the complex mol­ecules, resulting in a two-dimensional supra­molecular structure parallel to (001).

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