Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 10 (October 2013)


metal-organic compounds



hy2636 scheme

Acta Cryst. (2013). E69, m525    [ doi:10.1107/S1600536813024021 ]

Bis[[mu]-1-(3,5-dichloropyridin-2-yl)-2-(pyridin-3-ylmethylidene)hydrazine]bis[(nitrato-[kappa]O)silver(I)] acetonitrile disolvate

Y. Guo and H. Cai

Abstract: In the centrosymmetric binuclear title complex, [Ag2(NO3)2(C11H8Cl2N4)2]·2CH3CN, the AgI atom is four-coordinated and exhibits a highly distorted tetrahedral coordination sphere defined by three N atoms from two 1-(3,5-dichloropyridin-2-yl)-2-(pyridin-3-ylmethylidene)hydrazine ligands and one O atom from a nitrate anion. Intermolecular N-H...O hydrogen bonds link the complex molecules, resulting in a two-dimensional supramolecular structure parallel to (001).


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