Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 10 (October 2013)


metal-organic compounds



lh5644 scheme

Acta Cryst. (2013). E69, m526    [ doi:10.1107/S1600536813023076 ]

Tricarbonylchlorido(6',7'-dihydro-5'H-spiro[cyclopentane-1,6'-dipyrido[3,2-d:2',3'-f][1,3]diazepine]-[kappa]2N1,N11)rhenium(I)

O. R. Clegg, L. P. Harding, J. W. Miller and C. R. Rice

Abstract: In the title compound, [ReCl(C15H16N4)(CO)3], the ReI ion is coordinated in a distorted octahedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclopentane group is orientated in a transoid fashion with respect to the chloride ligand. The dihedral angle between the pryridine rings is 10.91 (12)°. In the crystal, N-H...Cl hydrogen bonds link complex molecules, forming a two-dimensional network parallel to (001).


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