Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 10 (October 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m526    [ doi:10.1107/S1600536813023076 ]


O. R. Clegg, L. P. Harding, J. W. Miller and C. R. Rice

Abstract: In the title compound, [ReCl(C15H16N4)(CO)3], the ReI ion is coordinated in a distorted octa­hedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclo­pentane group is orientated in a transoid fashion with respect to the chloride ligand. The dihedral angle between the pryridine rings is 10.91 (12)°. In the crystal, N-H...Cl hydrogen bonds link complex mol­ecules, forming a two-dimensional network parallel to (001).

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