Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 10 (October 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m537    [ doi:10.1107/S1600536813024653 ]

Bis[1-meth­oxy-2,2,2-tris­(pyrazol-1-yl-[kappa]N2)ethane]­nickel(II) bis­(tri­fluoro­methane­sulfonate) methanol disolvate

G. Lyubartseva, S. Parkin and U. P. Mallik

Abstract: In the title salt, [Ni(C12H14N6O)2](CF3SO3)2·2CH3OH, the NiII ion is coordinated by six N atoms from two tridentate 1-meth­oxy-2,2,2-tris­(pyrazol-1-yl)ethane ligands in a distorted octa­hedral geometry. The NiII ion is situated on an inversion centre. The Ni-N distances range from 2.0589 (19) to 2.0757 (19) Å, intra-ligand N-Ni-N angles range from 84.50 (8) to 85.15 (8)°, and adjacent inter-ligand N-Ni-N angles range between 94.85 (8) and 95.50 (8)°. In the crystal, O-H...O hydrogen bonds between methanol solvent mol­ecules and tri­fluoro­methane­sulfonate anions are observed.

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