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Volume 69 
Part 10 
Page m558  
October 2013  

Received 29 August 2013
Accepted 19 September 2013
Online 25 September 2013

Key indicators
Single-crystal X-ray study
T = 293 K
Mean [sigma](C-C) = 0.004 Å
R = 0.037
wR = 0.101
Data-to-parameter ratio = 14.9
Details
Open access

Poly[[mu]5-(4-methoxybenzenesulfonato)-sodium]

aDepartment of Chemistry, Faculty of Science, Prince of Songkla University, Hat-Yai, Songkhla 90112, Thailand,bFaculty of Traditional Thai Medicine, Prince of Songkla University, Hat-Yai, Songkhla 90112, Thailand, and cX-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia
Correspondence e-mail: suchada.c@psu.ac.th

In the title complex, [Na(C7H7O4S)]n, the NaI ion is coordinated in a slightly distorted pentagonal-bipyramidal environment by seven O atoms [Na-O = 2.3198 (16)-2.5585 (17) Å]. The 4-methoxybenzenesulfonate anions act as bis-chelating and bridging ligands, forming a two-dimensional polymer parallel to (001), which is further linked into a three-dimensional network by weak C-H...O hydrogen bonds.

Related literature

For the appplications of aromatic sulfonic acids, see: Babu et al. (2003[Babu, K. S., Raju, B. C., Srinivas, P. V., Rao, A. S., Kumar, S. P. & Rao, J. M. (2003). Chem. Lett. 32, 704-705.]); Chanawanno et al. (2010[Chanawanno, K., Chantrapromma, S., Anantapong, T. & Kanjana-Opas, A. (2010). Lat. Am. J. Pharm. 29, 1166-1170.]); King (1991[King, J. F. (1991). The Chemistry of Sulphonic Acids, Esters and their Derivatives, edited by S. Patai & Z. Rappoport, pp. 249-258. Chichester: Wiley.]); Ruanwas et al. (2010[Ruanwas, P., Kobkeatthawin, T., Chantrapromma, S., Fun, H.-K., Philip, R., Smijesh, N., Padaki, M. & Isloor, A. M. (2010). Synth. Met. 160, 819-824.]); Schöngut et al. (2011[Schöngut, M., Grof, Z. & Stepánek, F. (2011). Ind. Eng. Chem. Res. 50, 11576-11584.]); Siril et al. (2007[Siril, P. F., Davison, A. D., Randhawa, J. K. & Brown, D. R. (2007). J. Mol. Catal. A Chem. 267, 72-78.]); Taylor et al. (2006[Taylor, G. E., Gosling, M. & Pearce, A. (2006). J. Chromatogr. A, 1119, 231-237.]). For a related structure, see: Smith et al. (2004[Smith, G., Wermuth, U. D., Young, D. J. & Healy, P. C. (2004). Acta Cryst. E60, m836-m838.]). For standard bond-lengths, see: Allen et al. (1987[Allen, F. H., Kennard, O., Watson, D. G., Brammer, L., Orpen, A. G. & Taylor, R. (1987). J. Chem. Soc. Perkin Trans. 2, pp. S1-19.]).

[Scheme 1]

Experimental

Crystal data
  • [Na(C7H7O4S)]

  • Mr = 210.19

  • Orthorhombic, P b c a

  • a = 8.3121 (8) Å

  • b = 6.0287 (6) Å

  • c = 35.930 (3) Å

  • V = 1800.5 (3) Å3

  • Z = 8

  • Mo K[alpha] radiation

  • [mu] = 0.38 mm-1

  • T = 293 K

  • 0.54 × 0.46 × 0.22 mm

Data collection
  • Bruker APEXII CCD area detector diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2009[Bruker (2009). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.819, Tmax = 0.920

  • 8793 measured reflections

  • 1769 independent reflections

  • 1720 reflections with I > 2[sigma](I)

  • Rint = 0.022

Refinement
  • R[F2 > 2[sigma](F2)] = 0.037

  • wR(F2) = 0.101

  • S = 1.20

  • 1769 reflections

  • 119 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 0.28 e Å-3

  • [Delta][rho]min = -0.28 e Å-3

Table 1
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
C6-H6A...O1i 0.93 2.37 3.282 (3) 165
C7-H7A...O4ii 0.96 2.56 3.407 (4) 148
Symmetry codes: (i) [-x+{\script{3\over 2}}, y+{\script{1\over 2}}, z]; (ii) [-x+1, y+{\script{1\over 2}}, -z+{\script{3\over 2}}].

Data collection: APEX2 (Bruker, 2009[Bruker (2009). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2009[Bruker (2009). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL and Mercury (Macrae et al., 2006[Macrae, C. F., Edgington, P. R., McCabe, P., Pidcock, E., Shields, G. P., Taylor, R., Towler, M. & van de Streek, J. (2006). J. Appl. Cryst. 39, 453-457.]); software used to prepare material for publication: SHELXTL, PLATON (Spek, 2009[Spek, A. L. (2009). Acta Cryst. D65, 148-155.]), Mercury and publCIF (Westrip, 2010[Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.]).


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: LH5648 ).


Acknowledgements

The authors thank Prince of Songkla University for generous support. The authors also thank the Universiti Sains Malaysia for the APEX DE2012 grant No.1002/PFIZIK/910323.

References

Allen, F. H., Kennard, O., Watson, D. G., Brammer, L., Orpen, A. G. & Taylor, R. (1987). J. Chem. Soc. Perkin Trans. 2, pp. S1-19.
Babu, K. S., Raju, B. C., Srinivas, P. V., Rao, A. S., Kumar, S. P. & Rao, J. M. (2003). Chem. Lett. 32, 704-705.  [CrossRef] [ChemPort]
Bruker (2009). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Chanawanno, K., Chantrapromma, S., Anantapong, T. & Kanjana-Opas, A. (2010). Lat. Am. J. Pharm. 29, 1166-1170.  [ChemPort]
King, J. F. (1991). The Chemistry of Sulphonic Acids, Esters and their Derivatives, edited by S. Patai & Z. Rappoport, pp. 249-258. Chichester: Wiley.
Macrae, C. F., Edgington, P. R., McCabe, P., Pidcock, E., Shields, G. P., Taylor, R., Towler, M. & van de Streek, J. (2006). J. Appl. Cryst. 39, 453-457.  [Web of Science] [CrossRef] [ChemPort] [IUCr Journals]
Ruanwas, P., Kobkeatthawin, T., Chantrapromma, S., Fun, H.-K., Philip, R., Smijesh, N., Padaki, M. & Isloor, A. M. (2010). Synth. Met. 160, 819-824.  [Web of Science] [CSD] [CrossRef] [ChemPort]
Schöngut, M., Grof, Z. & Stepánek, F. (2011). Ind. Eng. Chem. Res. 50, 11576-11584.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [ChemPort] [IUCr Journals]
Siril, P. F., Davison, A. D., Randhawa, J. K. & Brown, D. R. (2007). J. Mol. Catal. A Chem. 267, 72-78.  [Web of Science] [CrossRef] [ChemPort]
Smith, G., Wermuth, U. D., Young, D. J. & Healy, P. C. (2004). Acta Cryst. E60, m836-m838.  [CSD] [CrossRef] [ChemPort] [IUCr Journals]
Spek, A. L. (2009). Acta Cryst. D65, 148-155.  [Web of Science] [CrossRef] [ChemPort] [IUCr Journals]
Taylor, G. E., Gosling, M. & Pearce, A. (2006). J. Chromatogr. A, 1119, 231-237.  [Web of Science] [CrossRef] [PubMed] [ChemPort]
Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.  [Web of Science] [CrossRef] [ChemPort] [IUCr Journals]


Acta Cryst (2013). E69, m558  [ doi:10.1107/S1600536813025919 ]

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