Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 10 (October 2013)


metal-organic compounds



lh5648 scheme

Acta Cryst. (2013). E69, m558    [ doi:10.1107/S1600536813025919 ]

Poly[[mu]5-(4-methoxybenzenesulfonato)-sodium]

S. Chantrapromma, N. Boonnak and H.-K. Fun

Abstract: In the title complex, [Na(C7H7O4S)]n, the NaI ion is coordinated in a slightly distorted pentagonal-bipyramidal environment by seven O atoms [Na-O = 2.3198 (16)-2.5585 (17) Å]. The 4-methoxybenzenesulfonate anions act as bis-chelating and bridging ligands, forming a two-dimensional polymer parallel to (001), which is further linked into a three-dimensional network by weak C-H...O hydrogen bonds.


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