Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 10 (October 2013)


metal-organic compounds



lh5649 scheme

Acta Cryst. (2013). E69, m544    [ doi:10.1107/S1600536813024914 ]

Tetrakis(acetonitrile)copper(I) hydrogen oxalate-oxalic acid-acetonitrile (1/0.5/0.5)

A. T. Royappa, J. R. Stepherson, O. D. Vu, A. D. Royappa, C. L. Stern and P. Müller

Abstract: In the title compound, [Cu(CH3CN)4](C2HO4)·0.5C2H2O4·0.5CH3CN, the CuI ion is coordinated by the N atoms of four acetonitrile ligands in a slightly distorted tetrahedral environment. The oxalic acid molecule lies across an inversion center. The acetonitrile solvent molecule is disordered across an inversion center and was refined with half occupancy. In the crystal, the hydrogen oxalate anions and oxalic acid molecules are linked via O-H...O hydrogen bonds, forming chains along [010].


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