Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 10 (October 2013)


metal-organic compounds



lh5651 scheme

Acta Cryst. (2013). E69, m561    [ doi:10.1107/S160053681302610X ]

Bis(1,10-phenanthroline-[kappa]2N,N')(sulfato-[kappa]O)zinc(II) propane-1,2-diol monosolvate

K.-L. Zhong

Abstract: In the title compound, [Zn(SO4)(C12H8N2)2]·C3H8O2, the ZnII ion is in a distorted square-pyramidal coordination environment composed of four N atoms from two chelating 1,10-phenanthroline ligands and one O atom from a monodentate sulfate ligand. The ZnII ion lies on a twofold rotation axis. The sulfate ligand and propane-1,2-diol molecules are disordered across the twofold rotation axis. The dihedral angle between the two chelating N2C2 groups is 83.26 (13)°. In the crystal, the complex molecule and the propane-1,2-diol molecule are connected through a pair of O-H...O hydrogen bonds.


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