Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 10 (October 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m530-m531    [ doi:10.1107/S1600536813021880 ]

(2,3,5,6-Tetra­fluoro­phenolato)[5,10,15,20-tetra­kis­(4-meth­oxy­phen­yl)porphyrinato]iron(III) cyclo­hexane monosolvate

N. Xu, D. R. Powell and G. B. Richter-Addo

Abstract: The title compound, [Fe(C6HF4O)(C48H36N4O4)]·C6H12, represents a five-coordinate iron(III) porphyrin complex in a square-pyramidal geometry with a tetra­fluoro­phenolate anion as the axial ligand. The FeIII atom is displaced by 0.364 (2) Å from the 24-atom mean plane of the porphyrinate ring towards the tetra­fluoro phenolate anion. The average Fe-N distance is 2.053 (2) Å and the Fe-O distance is 1.883 (2) Å. A porphyrin aryl H atom points in the general direction of the phenoxide ring. The mean plane separation between the 24-atom porphyrin planes of two adjacent porphyrin rings is ~3.7 Å, and the lateral shift is ~3.5 Å resu, ting in an Fe...Fe separation of 5.6167 (14) Å.

htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file (145.8 kbytes)
[ doi:10.1107/S1600536813021880/ng5339sup0.html ]
Supplementary materials


To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster