Acta Cryst. (2013). E69, o1579 [ doi:10.1107/S1600536813025750 ]
Abstract: In the title compound, C12H16BrNO2, the dioxane ring adopts a chair conformation and its mean plane makes a dihedral angle of 60.63 (12)° with the 4-bromophenyl ring. In the crystal, molecules are linked by pairs of N-HO hydrogen bonds, forming inversion dimers with an R22(8) ring motif. These dimers are consolidated by pairs of C-HO hydrogen bonds with an R22(16) ring motif. Adjacent dimers are connected via C-HO hydrogen bonds, forming infinite chains propagating along the c-axis direction.
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