Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 10 (October 2013)


metal-organic compounds



wm2764 scheme

Acta Cryst. (2013). E69, m539-m540    [ doi:10.1107/S1600536813024343 ]

Dichloridodiphenylbis(thiourea-[kappa]S)tin(IV)

Y. Sow, L. Diop, K. C. Molloy and G. Kociok-Köhn

Abstract: The title compound, [Sn(C6H5)2Cl2(CH4N2S)2], has been obtained from the reaction between Sn(C6H5)2Cl2 and SC(NH2)2. The asymmetric unit consists of one half of the molecular unit, the remainder generated by a twofold rotation axis located along the Cl-Sn-Cl bonds. The SnIV atom is coordinated by two phenyl groups, two Cl atoms and two thiourea ligands in an all trans octahedral C2Cl2S2 environment. Individual molecules are connected through N-H...Cl hydrogen bonds, leading to a three-dimensional network structure. Intramolecular N-H...Cl hydrogen bonds are also present.


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