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Volume 69 
Part 10 
Page m541  
October 2013  

Received 24 July 2013
Accepted 27 August 2013
Online 12 September 2013

Key indicators
Single-crystal X-ray study
T = 298 K
Mean [sigma](N-C) = 0.003 Å
R = 0.027
wR = 0.075
Data-to-parameter ratio = 15.4
Details
Open access

Poly[tetramethylammonium [tri-[mu]2-formato-[kappa]6O:O'-manganate(II)]]

aSchool of Chemistry and Material Science, Shanxi Normal University, Linfen 041004, People's Republic of China
Correspondence e-mail: dangqq820116@163.com

In the title compound, {(C4H12N)[Mn(HCO2)3]}n, the MnII atom lies on an inversion centre and is coordinated by O-atom donors from the three double-bridging formate ligands, one of which lies across a crystallographic mirror plane, giving a slightly distorted octahedral coordination sphere. A three-dimensional NaCl-type framework is generated in which the tetramethylammonium cations, which lie across mirror planes and occupy the cavities in the polymer structure, form weak C-H...O hydrogen bonds with the formate ligands.

Related literature

For related structures, see: Gao & Ng (2010[Gao, S. & Ng, S. W. (2010). Acta Cryst. E66, m1599.]); Wang et al. (2004[Wang, Z. M., Zhang, B., Otsuka, T., Inoue, K., Kobayashi, H. & Kurmoo, M. (2004). Dalton Trans. pp. 2209-2216.], 2010[Wang, Z. M., Hu, K. L., Gao, S. & Kobayashi, H. (2010). Adv. Mater. 22, 1526-1533.]). For background to the properties of structures with metal-formate frameworks templated by protonated amines, see: Liu et al. (2012[Liu, B., Shang, R. H. K. L., Wang, Z. M. & Gao, S. (2012). Inorg. Chem. 24, 13363-13372.]); Zhang et al. (2007[Zhang, B., Wang, Z. M., Kurmoo, M., Gao, S., Inoue, K. & Kobayashi, H. (2007). Adv. Funct. Mater. 17, 577-584.]).

[Scheme 1]

Experimental

Crystal data
  • (C4H12N)[Mn(HCO2)3]

  • Mr = 264.14

  • Orthorhombic, P n m a

  • a = 8.926 (4) Å

  • b = 12.767 (6) Å

  • c = 9.196 (4) Å

  • V = 1048.0 (8) Å3

  • Z = 4

  • Mo K[alpha] radiation

  • [mu] = 1.27 mm-1

  • T = 298 K

  • 0.22 × 0.22 × 0.15 mm

Data collection
  • Bruker SMART CCD area-detector diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2007[Bruker (2007). SAINT-Plus, SMART and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.768, Tmax = 0.833

  • 5907 measured reflections

  • 1189 independent reflections

  • 1012 reflections with I > 2[sigma](I)

  • Rint = 0.023

Refinement
  • R[F2 > 2[sigma](F2)] = 0.027

  • wR(F2) = 0.075

  • S = 0.98

  • 1189 reflections

  • 77 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 0.27 e Å-3

  • [Delta][rho]min = -0.43 e Å-3

Table 1
Selected bond lengths (Å)

Mn1-O1 2.2176 (16)
Mn1-O2 2.2010 (15)
Mn1-O3i 2.2089 (16)
Mn1-O1ii 2.2176 (16)
Mn1-O2ii 2.2010 (15)
Mn1-O3iii 2.2089 (16)
Symmetry codes: (i) [-x+{\script{1\over 2}}, -y+1, z+{\script{1\over 2}}]; (ii) -x+1, -y+1, -z+1; (iii) [x+{\script{1\over 2}}, y, -z+{\script{1\over 2}}].

Table 2
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
C3-H3B...O3ii 0.96 2.40 3.355 (3) 176
C4-H4B...O2iv 0.96 2.41 3.367 (3) 171
C5-H5B...O1iii 0.96 2.41 3.349 (3) 167
Symmetry codes: (ii) -x+1, -y+1, -z+1; (iii) [x+{\script{1\over 2}}, y, -z+{\script{1\over 2}}]; (iv) [-x+1, y+{\script{1\over 2}}, -z+1].

Data collection: SMART (Bruker, 2007[Bruker (2007). SAINT-Plus, SMART and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT-Plus (Bruker, 2007[Bruker (2007). SAINT-Plus, SMART and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: DIAMOND (Brandenburg & Putz, 2006[Brandenburg, K. & Putz, H. (2006). DIAMOND. Crystal Impact, Bonn, Germany.]); software used to prepare material for publication: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]).


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: ZS2272 ).


Acknowledgements

The authors thank the Shanxi Province Science Foundation for Youths (2012021008-2), the National Natural Science Foundation of China (21101102) and the National Science Fund for Distinguished Young Scholars (20925101).

References

Brandenburg, K. & Putz, H. (2006). DIAMOND. Crystal Impact, Bonn, Germany.
Bruker (2007). SAINT-Plus, SMART and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Gao, S. & Ng, S. W. (2010). Acta Cryst. E66, m1599.  [CSD] [CrossRef] [IUCr Journals]
Liu, B., Shang, R. H. K. L., Wang, Z. M. & Gao, S. (2012). Inorg. Chem. 24, 13363-13372.  [Web of Science] [CSD] [CrossRef]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [ChemPort] [IUCr Journals]
Wang, Z. M., Hu, K. L., Gao, S. & Kobayashi, H. (2010). Adv. Mater. 22, 1526-1533.  [Web of Science] [CrossRef] [ChemPort] [PubMed]
Wang, Z. M., Zhang, B., Otsuka, T., Inoue, K., Kobayashi, H. & Kurmoo, M. (2004). Dalton Trans. pp. 2209-2216.  [CSD] [CrossRef]
Zhang, B., Wang, Z. M., Kurmoo, M., Gao, S., Inoue, K. & Kobayashi, H. (2007). Adv. Funct. Mater. 17, 577-584.  [CSD] [CrossRef] [ChemPort]


Acta Cryst (2013). E69, m541  [ doi:10.1107/S1600536813024045 ]

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