[Open access]

[Contents scheme]

Acta Cryst. (2013). E69, m600
[ doi:10.1107/S1600536813027852 ]

Di-[mu]-hydroxido-[kappa]4O:O-di-[mu]-perchlorato-[kappa]4O:O'-bis­[(2,2'-bi­pyridine-[kappa]2N,N')copper(II)]

B. Saravanan, A. Jayamani, N. Sengottuvelan, G. Chakkaravarthi and V. Manivannan

Abstract: In the title binuclear copper(II) complex, [Cu2(ClO4)2(OH)2(C10H8N2)2], the CuII ion is coordinated in the form of a Jahn-Teller distorted octahedron by two bi­pyridine N atoms, two perchlorate O atoms and two hydroxide O atoms, and displays a distorted octa­hedral geometry. The mol­ecule belongs to the symmetry point group C2h. The CuII ion is located on a twofold rotation axis and the hydroxide and perchlorate ligands are located on a mirror plane. Within the dinuclear mol­ecule, the Cu...Cu separation is 2.8614 (7) Å. The crystal structure exhibits O-H...O, C-H...O and [pi]-[pi] [centroid-centroid distance = 3.5374 (13) Å] inter­actions.


Copyright © International Union of Crystallography
IUCr Webmaster