Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 11 (November 2013)


inorganic compounds



Acta Cryst. (2013). E69, i77-i78    [ doi:10.1107/S1600536813028602 ]

Sodium selenite penta­hydrate, Na2SeO3·5H2O

K. Mereiter

Abstract: In the crystal structure of Na2SeO3·5H2O [disodium selen­ate(IV) penta­hydrate], two Se, two selenite O atoms and one water O atom are located on a mirror plane, and one water O atom is located on a twofold rotation axis. The coordination of one Na+ cation is distorted trigonal bipyramidal, formed by three equatorial H2O ligands and two axial selenite O atoms. The other Na+ cation has an octa­hedral coordination by six water mol­ecules. The two independent SeO3 groups form almost undistorted trigonal pyramids, with Se-O bond lengths in the range 1.6856 (7)-1.7202 (10) Å and O-Se-O angles in the range 101.98 (3)-103.11 (5)°, and both are [mu]2-O:O-bonded to a pair of Na+ cations. Hydrogen bonds involving all water molecules and selenite O atoms consolidate the crystal packing. Although anhydrous Na2SeO3 and Na2TeO3 are isotypic, the title compound is surprisingly not isotypic with Na2TeO3·5H2O. In the tellurite hydrate, all Na+ cations have an octa­hedral coordination and the TeO3 groups are bonded to Na+ only via one of their three O atoms.


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